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Passive sampling methods for contaminated sediments: state of the science for metals.

ABSTRACT: "Dissolved" concentrations of contaminants in sediment porewater (Cfree ) provide a more relevant exposure metric for risk assessment than do total concentrations. Passive sampling methods (PSMs) for estimating Cfree offer the potential for cost-efficient and accurate in situ characterization of Cfree for inorganic sediment contaminants. In contrast to the PSMs validated and applied for organic contaminants, the various passive sampling devices developed for metals, metalloids, and some nonmetals (collectively termed "metals") have been exploited to a limited extent, despite recognized advantages that include low detection limits, detection of time-averaged trends, high spatial resolution, information about dissolved metal speciation, and the ability to capture episodic events and cyclic changes that may be missed by occasional grab sampling. We summarize the PSM approaches for assessing metal toxicity to, and bioaccumulation by, sediment-dwelling biota, including the recognized advantages and limitations of each approach, the need for standardization, and further work needed to facilitate broader acceptance and application of PSM-derived information by decision makers.

SUBMITTER: Peijnenburg WJ

PROVIDER: S-EPMC4238822 | biostudies-other | 2014 Apr

REPOSITORIES: biostudies-other

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Passive sampling methods for contaminated sediments: state of the science for metals.

Peijnenburg Willie J G M WJ Teasdale Peter R PR Reible Danny D Mondon Julie J Bennett William W WW Campbell Peter G C PG

Integrated environmental assessment and management 20140127 2

"Dissolved" concentrations of contaminants in sediment porewater (Cfree ) provide a more relevant exposure metric for risk assessment than do total concentrations. Passive sampling methods (PSMs) for estimating Cfree offer the potential for cost-efficient and accurate in situ characterization of Cfree for inorganic sediment contaminants. In contrast to the PSMs validated and applied for organic contaminants, the various passive sampling devices developed for metals, metalloids, and some nonmetal ...[more]

PMID: 24470168

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Project description:Objectives:In an occupational environment, passive sampling could be an alternative to active sampling with pumps for sampling of dust. One passive sampler is the University of North Carolina passive aerosol sampler (UNC sampler). It is often analysed by microscopic imaging. Promising results have been shown for particles above 2.5 µm, but indicate large underestimations for PM2.5. The aim of this study was to evaluate, and possibly improve, the UNC sampler for stationary sampling in a working environment. Methods:Sampling was carried out at 8-h intervals during 24 h in four locations in an open pit mine with UNC samplers, respirable cyclones, PM10 and PM2.5 impactors, and an aerodynamic particle sizer (APS). The wind was minimal. For quantification, two modifications of the UNC sampler analysis model, UNC sampler with hybrid model and UNC sampler with area factor, were compared with the original one, UNC sampler with mesh factor derived from wind tunnel experiments. The effect of increased resolution for the microscopic imaging was examined. Results:Use of the area factor and a higher resolution eliminated the underestimation for PM10 and PM2.5. The model with area factor had the overall lowest deviation versus the impactor and the cyclone. The intraclass correlation (ICC) showed that the UNC sampler had a higher precision and better ability to distinguish between different exposure levels compared to the cyclone (ICC: 0.51 versus 0.24), but lower precision compared to the impactor (PM10: 0.79 versus 0.99; PM2.5: 0.30 versus 0.45). The particle size distributions as calculated from the different UNC sampler analysis models were visually compared with the distributions determined by APS. The distributions were obviously different when the UNC sampler with mesh factor was used but came to a reasonable agreement when the area factor was used. Conclusions:High resolution combined with a factor based on area only, results in no underestimation of small particles compared to impactors and cyclones and a better agreement with the APS's particle size distributions. The UNC sampler had lower precision than the impactors, but higher than the respirable cyclone. The UNC sampler with area factor could be used for PM2.5, PM10 and respirable fraction measurements in this working environment without wind.

Project description:Environmental management often aims at sustainability and at implementing goals such as the United Nations Sustainable Development Goals (SDGs). Several of these goals rely upon healthy sediments, implying that contaminated sediments need to be addressed in environmental management. In Sweden, the SDGs and national environmental objectives are meant to be central in environmental management. However, in environmental risk assessment (ERA) for contaminated sediments, it is not clear to assessors or authorities in Sweden which goals to consider and how. In the present study, we explore which environmental goals ERAs of contaminated sediment should consider, according to representatives from Swedish regulatory and advisory authorities, and to what extent ERAs consider those goals in practice in Sweden. The identified goals indicated that protection of aquatic ecosystems and associated services is a main priority for the authorities. The ERAs analyzed showed that most identified goals were addressed, albeit not consistently. Furthermore, risk assessors seem to put less weight on ecological aspects than authorities do. This indicates that authorities need to stress the importance of environmental aspects and provide guidance on how to address them. Several environmental goals were found to be directly relevant to contaminated sediments and ERAs can contribute to their fulfillment, given that ERA is a basis for management decisions. However, practitioners need clearer guidance on which goals to address and how. Finally, there seems to be good potential for implementation of the SDGs in environmental management in Sweden, due to existing legislation based on sustainable development and well-anchored national environmental objectives that overlap with the SDGs. Integr Environ Assess Manag 2019;00:1-12. © 2019 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of Society of Environmental Toxicology & Chemistry (SETAC).

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Passive sampling methods for contaminated sediments: state of the science for metals.

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Passive sampling methods for contaminated sediments: state of the science for metals.

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