CFD convective flow simulation of the varying properties of CO2-H2O mixtures in geothermal systems.
Ontology highlight
ABSTRACT:
SUBMITTER: Yousefi S
PROVIDER: S-EPMC4386697 | biostudies-other | 2015
REPOSITORIES: biostudies-other
Similar Datasets
Project description:The effects of V and Ce concentrations (each varying in the 0-100% range) in vanadia-ceria multiphase systems are investigated for synthesis gas production via thermochemical redox cycles of CO2 and H2O splitting coupled to methane partial oxidation reactions. The oxidation of prepared oxygen carriers is performed by separate and sequential CO2 and H2O splitting reactions. Structural and chemical analyses of the mixed-metal oxides revealed important information about the Ce and V interactions affecting their crystal phases and redox characteristics. Pure CeO2 and pure V2O5 are found to offer the lowest and highest oxygen exchange capacities and syngas production performance, respectively. The mixed-oxide systems provide a balanced performance: their oxygen exchange capacity is up to 5 times higher than that of pure CeO2 while decreasing the extent of methane cracking. The addition of 25% V to CeO2 results in an optimum mixture of CeO2 and CeVO4 for enhanced CO2 and H2O splitting. At higher V concentrations, cyclic carbide formation and oxidation result in a syngas yield higher than that for pure CeO2.
| S-EPMC7008271 | biostudies-literature
Project description:Therapeutic complement inhibition is a major focus for novel drug development. Of upstream targets, factor D (FD) is appealing because it circulates in plasma at low concentrations and has a single function: to cleave factor B to generate C3 convertase of the alternative pathway (AP). Mice with a targeted deletion of factor H (FH; Cfh-/- mice) develop C3 glomerulopathy (C3G) due to uncontrolled AP activity. To assess the impact of FD inhibition, we studied Cfh-/- Cfd-/- mice. We show that C3G in Cfh-/- mice is not rescued by removing FD. We used serum from Cfh-/- Cfd-/- mice to demonstrate that residual AP function occurs even when both FD and FH are missing and that hemolytic activity is present due to the action of C3(H2O). We propose that uncontrolled tick-over leads to slow activation of the AP in Cfh-/- Cfd-/- mice and that a minimal threshold of FH is necessary if tissue deposition of C3 is to be prevented. The FD/FH ratio dictates serum C3 level and renal C3b deposition. In C3G patients with chronic renal disease, the FD/FH ratio correlates inversely with C3 and C5 serum levels, suggesting that continuous AP control may be difficult to achieve by targeting FD.
| S-EPMC7253029 | biostudies-literature
Project description:In this work, we propose numerical methodologies to combine detailed microkinetic modeling and Eulerian-Lagrangian methods for the multiscale simulation of fluidized bed reactors. In particular, we couple the hydrodynamics description by computational fluid dynamics and the discrete element method (CFD-DEM) with the detailed surface chemistry by means of microkinetic modeling. The governing equations for the gas phase are solved through a segregated approach. The mass and energy balances for each catalytic particle, instead, are integrated adopting both the coupled and the operator-splitting approaches. To reduce the computational burden associated with the microkinetic description of the surface chemistry, in situ adaptive tabulation (ISAT) is employed together with operator-splitting. The catalytic partial oxidation of methane and steam reforming on Rh are presented as a showcase to assess the capability of the methods. An accurate description of the gas and site species is achieved along with up to 4 times speed-up of the simulation, thanks to the combined effect of operator-splitting and ISAT. The proposed approach represents an important step for the first-principles based multiscale analysis of fluidized reactive systems.
| S-EPMC6333279 | biostudies-literature
Project description:This paper presents the data obtained from the CFD simulation of a pico-hydraulic turbine designed for electric power generation in residential units. Pico-hydro turbine systems are a booming option that seeks to take advantage of small waterfalls and/or streams to generate electricity in a clean way. The data collection process was carried out through simulations developed to a model created in SolidWorks, with the help of the ANSYS CFX software in which the solver configuration was adjusted to the parameters suggested by the manufacturer's manuals (ANSYS) and the boundary conditions were determined based on the current regulatory standards for drinking water systems for Colombia. These boundary conditions influence the operation of the turbine, which is why three runs were carried out corresponding to three points of operation and to obtain the output pressure, the fall of the turbine and the hydraulic power that the device would utilise. The data, acquired in a strict manner, offers potential support for further research in the area and the possible manufacture of prototypes. It also encourages the development of simulations and laboratory tests of this type of device in which geometric factors or operating conditions could be modified.
| S-EPMC7721606 | biostudies-literature
Project description:Complex intra-molecular interactions and the hydrogen-bonding network in H2O-volatile mixtures play critical roles in many dynamics processes in physical chemistry, biology, and Earth and planetary sciences. We used high pressure Raman spectroscopy to study the pressure evolution of vibrational frequencies and bonding behavior in H2O-CH3OH mixtures. We found that the presence of low CH3OH content in H2O increases the transition pressure where water crystallizes to ice VI, but does not significantly change the pressure where ice VI transforms to ice VII. Furthermore, the stiffening rates of C-H stretching frequencies dω/dP in CH3OH significantly decrease upon the crystallization of water, and the softening rates of the O-H stretching frequencies of ice VII are suppressed over a narrow pressure range, after which the frequencies of these modes shift with pressure in ways similar to pure CH3OH and ice VII, respectively. Such complex pressure evolution of Raman frequencies along with pronounced variations in Raman intensities of CH3OH within the sample, and the hysteresis of the water-ice VI phase transition suggest pressure-induced segregation of low content CH3OH from ice VII. These findings indicate the significant influence of volatiles on the crystallization of sub-surface ocean and thermal evolution within large icy planets and satellites.
| S-EPMC4336930 | biostudies-other
Project description:Supercritical water oxidation (SCWO) is an effective technique to treat wet organic wastes. Its modeling requires an accurate calculation of thermodynamic properties. In this work an equation of state (EOS) is proposed which accurately predicts the thermodynamic state of mixtures of water, oxygen, nitrogen, and carbon dioxide for a wide range of compositions, temperatures, and pressures including supercritical conditions. The EOS includes a volume translation, an evolved α -function and non-quadratic mixing rules. The introduced parameters are regressed to experimental data. From the pressure-explicit EOS, enthalpy, specific heats at constant volume and constant pressure, and fugacity coefficients are derived and calculated. The binary mixtures H2O/O2 , H2O/N2 , H2O/CO2 , N2/CO2 as well as the ternary mixture H2O/O2/N2 are well predicted by the proposed EOS with relative errors below 10% and 15%, respectively. The region of low temperature and high pressure is most difficult to predict with relative errors up to 20%.
| S-EPMC6919335 | biostudies-literature
Project description:In the present work Computational Fluid Dynamics (CFD) was used to study the flow field and particle dynamics in an internal spin-filter (SF) bioreactor system. Evidence of a radial exchange flow through the filter mesh was detected, with a magnitude up to 130-fold higher than the perfusion flow, thus significantly contributing to radial drag. The exchange flow magnitude was significantly influenced by the filter rotation rate, but not by the perfusion flow, within the ranges evaluated. Previous reports had only given indirect evidences of this exchange flow phenomenon in spin-filters, but the current simulations were able to quantify and explain it. Flow pattern inside the spin-filter bioreactor resembled a typical Taylor-Couette flow, with vortices being formed in the annular gap and eventually penetrating the internal volume of the filter, thus being the probable reason for the significant exchange flow observed. The simulations also showed that cells become depleted in the vicinity of the mesh due to lateral particle migration. Cell concentration near the filter was approximately 50% of the bulk concentration, explaining why cell separation achieved in SFs is not solely due to size exclusion. The results presented indicate the power of CFD techniques to study and better understand spin-filter systems, aiming at the establishment of effective design, operation and scale-up criteria.
| S-EPMC2795145 | biostudies-other
Project description:Hydrated singly charged metal ions doped with carbon dioxide, Mg2+(CO2)-(H2O) n, in the gas phase are valuable model systems for the electrochemical activation of CO2. Here, we study these systems by Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry combined with ab initio calculations. We show that the exchange reaction of CO2 with O2 proceeds fast with bare Mg+(CO2), with a rate coefficient kabs?=?1.2 × 10-10?cm3?s-1, while hydrated species exhibit a lower rate in the range of kabs = (1.2-2.4) × 10-11?cm3?s-1 for this strongly exothermic reaction. Water makes the exchange reaction more exothermic but, at the same time, considerably slower. The results are rationalized with a need for proper orientation of the reactants in the hydrated system, with formation of a Mg2+(CO4)-(H2O) n intermediate while the activation energy is negligible. According to our nanocalorimetric analysis, the exchange reaction of the hydrated ion is exothermic by -1.7 ± 0.5?eV, in agreement with quantum chemical calculations.
| S-EPMC6331139 | biostudies-literature
Project description:Soil moisture can feed back on rainfall through the impact of surface fluxes on the environment in which convection develops. The vast majority of previous research has focused on the initiation of convection, but in many regions of the world, the majority of rain comes from remotely triggered mesoscale convective systems (MCSs). Here we conduct a systematic observational analysis of soil moisture feedbacks on propagating MCSs anywhere in the world and show a strong positive impact of drier soils on convection within mature MCSs. From thousands of storms captured in satellite imagery over the Sahel, we find that convective cores within MCSs are favored on the downstream side of dry patches ≥200 km across. The effect is particularly strong during the afternoon-evening transition when convection reaches its diurnal peak in intensity and frequency, with dry soils accounting for an additional one in five convective cores. Dry soil patterns intensify MCSs through a combination of convergence, increased instability, and wind shear, all factors that strengthen organized convection. These favorable conditions tend to occur in the vicinity of a surface-induced anomalous displacement of the Sahelian dry line/intertropical discontinuity, suggesting a strong link between dry line dynamics and soil moisture state. Our results have important implications for nowcasting of severe weather in the Sahel and potentially in other MCS hotspot regions of the world.
| S-EPMC7474668 | biostudies-literature
Project description:Surface-bound enzymes can act as pumps that drive large-scale fluid flows in the presence of their substrates or promoters. Thus, enzymatic catalysis can be harnessed for “on demand” pumping in nano- and microfluidic devices powered by an intrinsic energy source. The mechanisms controlling the pumping have not, however, been completely elucidated. Herein, we combine theory and experiments to demonstrate a previously unreported spatiotemporal variation in pumping behavior in urease-based pumps and uncover the mechanisms behind these dynamics. We developed a theoretical model for the transduction of chemical energy into mechanical fluid flow in these systems, capturing buoyancy effects due to the solution containing nonuniform concentrations of substrate and product. We find that the qualitative features of the flow depend on the ratios of diffusivities ?=D(P)/D(S) and expansion coefficients ?=?(P)/?(S) of the reaction substrate (S) and product (P). If ?>1 and ?>? (or if ?<1 and ?<? ), an unexpected phenomenon arises: the flow direction reverses with time and distance from the pump. Our experimental results are in qualitative agreement with the model and show that both the speed and direction of fluid pumping (i) depend on the enzyme activity and coverage, (ii) vary with the distance from the pump, and (iii) evolve with time. These findings permit the rational design of enzymatic pumps that accurately control the direction and speed of fluid flow without external power sources, enabling effective, self-powered fluidic devices.
| S-EPMC4791027 | biostudies-literature