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N-(2-Acetamido-2-de-oxy-?-d-gluco-pyranos-yl)-N-(3-azido-prop-yl)-O-methyl-hydroxyl-amine.

ABSTRACT: The structure of the title compound, C12H23N5O6, solved using adequate data from a thin crystal plate, confirmed that this useful glycoconjugate was obtained in the ring-closed ?-pyran-ose configuration with (4) C 1 conformation. The mol-ecules are bound by O-H?O(OH) hydrogen bonds, notably in a zigzag C(2) chain along the short b (screw) axis, supplemented with an R 2 (2)(12) O-H?O(carbon-yl) link along the a axis and other C(2) links. The absolute configuration was not unambiguously determined but was known from the synthetic chemistry, which used natural 2-acetamido-2-de-oxy-d-glucose as the starting material.

SUBMITTER: Munneke S

PROVIDER: S-EPMC4778837 | biostudies-other | 2016 Mar

REPOSITORIES: biostudies-other

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N-(2-Acetamido-2-de-oxy-β-d-gluco-pyranos-yl)-N-(3-azido-prop-yl)-O-methyl-hydroxyl-amine.

Munneke Stefan S Stocker Bridget L BL Timmer Mattie S M MS Gainsford Graeme J GJ

Acta crystallographica. Section E, Crystallographic communications 20160217 Pt 3

The structure of the title compound, C12H23N5O6, solved using adequate data from a thin crystal plate, confirmed that this useful glycoconjugate was obtained in the ring-closed β-pyran-ose configuration with (4) C 1 conformation. The mol-ecules are bound by O-H⋯O(OH) hydrogen bonds, notably in a zigzag C(2) chain along the short b (screw) axis, supplemented with an R 2 (2)(12) O-H⋯O(carbon-yl) link along the a axis and other C(2) links. The absolute configuration was not unambiguously determined ...[more]

PMID: 27006803

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