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Trichloridotris{N-[phen-yl(pyridin-2-yl)-methyl-idene]hydroxyl-amine-?N,N'}samarium(III).

ABSTRACT: The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl(3)N(6) donor set. The mol-ecular structure is stabilized by three intra-molecular O-H?Cl hydrogen bonds.

SUBMITTER: Lei T

PROVIDER: S-EPMC3297284 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Trichloridotris{N-[phen-yl(pyridin-2-yl)-methyl-idene]hydroxyl-amine-κN,N'}samarium(III).

Lei Tao T Chen Wenqian W Chen Yanmei Y Hu Bin B Li Yahong Y

Acta crystallographica. Section E, Structure reports online 20120229 Pt 3

The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl(3)N(6) donor set. The mol-ecular structure is stabilized by three intra-molecular O-H⋯Cl hydrogen bonds. ...[more]

PMID: 22412474

Similar Datasets

Trichloridotris{N-[phen-yl(pyridin-2-yl)methyl-idene]hydroxyl-amine-?(2)N,N'}neodymium(III).

Project description:In the title compound, [NdCl(3)(C(12)H(10)N(2)O)(3)], the central Nd(III) ion is nine-coordinated by six N atoms from three bidentate chelate N-[phen-yl(pyridin-2-yl)methyl-idene]hydroxyl-amine ligands and three Cl(-) ions, and displays a distorted tricapped trigonal prismatic geometry. The complex mol-ecules are stabilized by intra-molecular O-H?Cl hydrogen bonds.

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Project description:The whole of the title mol-ecule, C13H14ClNO, is disordered over two sets of sites with a refined occupancy ratio of 0.560?(6):0.440?(6). The oxime group having a C=N double bond adopts an E conformation. The dihedral angles between the rings (all atoms) are 89.5?(5) (major componenent) and 88.0?(6)° (minor component).

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N-(4-Methyl-phen-yl)-3-nitro-pyridin-2-amine.

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Crystal structure of (pyridin-2-yl-methyl-idene)(tri-phenyl-meth-yl)amine.

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N-Benzoyl-N-(3-methyl-phen-yl)-O-[2-(2-nitro-phen-yl)acet-yl]hydroxyl-amine.

Project description:In the title mol-ecule, C(22)H(18)N(2)O(5), the nitro-substituted ring makes a dihedral angle of 81.9 (1)° with the benzoyl ring and a dihedral angle of 12.1 (1)° with the methyl-substituted ring.

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