Ontology highlight
ABSTRACT:
SUBMITTER: Morales Torres G
PROVIDER: S-EPMC5390800 | biostudies-other | 2017 Apr
REPOSITORIES: biostudies-other
ChemistryOpen 20170123 2
A series of diphosphoramidites has been synthetized with a piperazine, homopiperazine, and an acyclic 1,2-diamine unit in the backbone. New compounds were tested alongside related <i>N</i>-acyl phosphoramidites as ligands in the Rh-catalyzed hydroformylation of <i>n</i>-octenes to investigate their influence on the activity and regioselectivity. A subsequent study of their hydrolysis stability revealed that the most stable ligands induced the highest activity in the catalytic reaction. ...[more]