Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Hierarchical Fibers with a Negative Poisson's Ratio for Tougher Composites.

ABSTRACT: In this paper, a new kind of hierarchical tube with a negative Poisson's ratio (NPR) is proposed. The first level tube is constructed by rolling up an auxetic hexagonal honeycomb. Then, the second level tube is produced by substituting the arm of the auxetic sheet with the first level tube and rolling it up. The Nth ( ) level tube can be built recursively. Based on the Euler beam theory, the equivalent elastic parameters of the NPR hierarchical tubes under small deformations are derived. Under longitudinal axial tension, instead of shrinking, all levels of the NPR hierarchical tubes expand in the transverse direction. Using these kinds of auxetic tubes as reinforced fibers in composite materials would result in a higher resistance to fiber pullout. Thus, this paper provides a new strategy for the design of fiber reinforced hierarchical bio-inspired composites with a superior pull-out mechanism, strength and toughness. An application with super carbon nanotubes concludes the paper.

SUBMITTER: Sun Y

PROVIDER: S-EPMC5452085 | biostudies-other | 2013 Feb

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Similar Datasets

Adenine as Epoxy Resin Hardener for Sustainable Composites Production with Recycled Carbon Fibers and Cellulosic Fibers.

Project description:In this work, Adenine is proposed, for the first time, as a cross-linker for epoxy resins. Adenine is an amino-substituted purine with heterocyclic aromatic structure showing both proton donors, and hydrogen bonding ability. DSC studies show that adenine is able to positively cross-link a biobased DGEBA-like commercial epoxy precursor with good thermal performance and a reaction mechanism based on a 1H NMR investigation has been proposed. The use of such a formulation to produce composite with recycled short carbon fibers (and virgin ones for the sake of comparison), as well as jute and linen natural fibers as sustainable reinforcements, leads to materials with high compaction and fiber content. The curing cycle was optimized for both carbon fiber and natural fiber reinforced materials, with the aim to achieve the better final properties. All composites produced display good thermal and mechanical properties with glass transition in the range of HT resins (Tg > 150 °C, E' =26 GPa) for the carbon fiber-based composites. The natural fiber-based composites display slightly lower performance that is nonetheless good compared with standard composite performance (Tg about 115-120 °C, E' = 7-9 GPa). The present results thus pave the way to the application of adenine as hardener system for composites production.

| S-EPMC7766952 | biostudies-literature

Tensan Silk-Inspired Hierarchical Fibers for Smart Textile Applications.

Project description:Tensan silk, a natural fiber produced by the Japanese oak silk moth ( Antherea yamamai, abbreviated to A. yamamai), features superior characteristics, such as compressive elasticity and chemical resistance, when compared to the more common silk produced from the domesticated silkworm, Bombyx mori ( B. mori). In this study, the "structure-property" relationships within A. yamamai silk are disclosed from the different structural hierarchies, confirming the outstanding toughness as dominated by the distinct mesoscale fibrillar architectures. Inspired by this hierarchical construction, we fabricated A. yamamai silk-like regenerated B. mori silk fibers (RBSFs) with mechanical properties (extensibility and modulus) comparable to natural A. yamamai silk. These RBSFs were further functionalized to form conductive RBSFs that were sensitive to force and temperature stimuli for applications in smart textiles. This study provides a blueprint in exploiting rational designs from A. yamanmai, which is rare and expensive in comparison to the common and cost-effective B. mori silk to empower enhanced material properties.

| S-EPMC6501189 | biostudies-literature

Bioactive hierarchical silk fibers created by bioinspired self-assembly.

Project description:Artificial recapitulation of the hierarchy of natural protein fibers is crucial to providing strategies for developing advanced fibrous materials. However, it is challenging due to the complexity of the natural environment. Inspired by the liquid crystalline spinning of spiders, we report the development of natural silk-like hierarchical fibers, with bundles of nanofibrils aligned in their long-axis direction, by self-assembly of crystallized silk fibroin (SF) droplets. The formation of self-assembled SF fibers is a process of coalesced droplets sprouting to form a branched fibrous network, which is similar to the development of capillaries in our body. The as-assembled hierarchical SF fibers are highly bioactive and can significantly enhance the spreading and growth of human umbilical vein endothelial cells compared to the natural SF fibers. This work could help to understand the natural silk spinning process of spiders and provides a strategy for design and development of advanced fibrous biomaterials for various applications.

| S-EPMC8062673 | biostudies-literature

Hybrid denture acrylic composites with nanozirconia and electrospun polystyrene fibers.

Project description:The processing and characterization of hybrid PMMA resin composites with nano-zirconia (ZrO2) and electrospun polystyrene (PS) polymer fibers were presented in this study. Reinforcement was selected with the intention to tune the physical and mechanical properties of the hybrid composite. Surface modification of inorganic particles was performed in order to improve the adhesion of reinforcement to the matrix. Fourier transform infrared spectroscopy (FTIR) provided successful modification of zirconia nanoparticles with 3-Methacryloxypropyltrimethoxysilane (MEMO) and bonding improvement between incompatible inorganic nanoparticles and PMMA matrix. Considerable deagglomeration of nanoparticles in the matrix occurred after the modification has been revealed by scanning electron microscopy (SEM). Microhardness increased with the concentration of modified nanoparticles, while the fibers were the modifier that lowers hardness and promotes toughness of hybrid composites. Impact test displayed increased absorbed energy after the PS electrospun fibers had been embedded. The optimized composition of the hybrid was determined and a good balance of thermal and mechanical properties was achieved.

| S-EPMC6919599 | biostudies-literature

Designing stable, hierarchical peptide fibers from block co-polypeptide sequences.

Project description:Natural materials, such as collagen, can assemble with multiple levels of organization in solution. Achieving a similar degree of control over morphology, stability and hierarchical organization with equilibrium synthetic materials remains elusive. For the assembly of peptidic materials the process is controlled by a complex interplay between hydrophobic interactions, electrostatics and secondary structure formation. Consequently, fine tuning the thermodynamics and kinetics of assembly remains extremely challenging. Here, we synthesized a set of block co polypeptides with varying hydrophobicity and ability to form secondary structure. From this set we select a sequence with balanced interactions that results in the formation of high-aspect ratio thermodynamically favored nanotubes, stable between pH 2 and 12 and up to 80 °C. This stability permits their hierarchical assembly into bundled nanotube fibers by directing the pH and inducing complementary zwitterionic charge behavior. This block co-polypeptide design strategy, using defined sequences, provides a straightforward approach to creating complex hierarchical peptide-based assemblies with tunable interactions.

| S-EPMC7449534 | biostudies-literature

Gas-Sensing Properties and Preparation of Waste Mask Fibers/ZnS Composites.

Project description:To realize the resource utilization of waste mask fibers (MF), a layer of ZnS nanoparticles was grown on MF by a one-step hydrothermal method, and a MF/ZnS sensor was successfully prepared. This is the first time that resource utilization of MF has been combined with the development of a high-performance gas sensor. The MF/ZnS sensor showed high sensitivity and recoverability to target vapors at room temperature. Compared with ZnS powder loaded on a ceramic substrate, the MF/ZnS composite responses to four analytes have been improved by 8.4~35.2 times. In addition, the time for the MF/ZnS sensor to complete one response-recovery cycle for all four analytes was less than 30 s. This should be attributed to the high gas permeability of the MF substrate, which made the ZnS particles loaded on the MF more fully exposed to contact with the target vapors. This work not only provides a simple and low-cost method to optimize the sensing performance of gas sensors but also provides a new way for the resource utilization of MF.Graphic abstractSupplementary informationThe online version contains supplementary material available at 10.1007/s11664-022-09644-1.

| S-EPMC9040696 | biostudies-literature

Enhancing the Mechanical Performance of Bleached Hemp Fibers Reinforced Polyamide 6 Composites: A Competitive Alternative to Commodity Composites.

Project description:Automotive and industrial design companies have profusely used commodity materials like glass fiber-reinforced polypropylene. These materials show advantageous ratios between cost and mechanical properties, but poor environmental yields. Natural fibers have been tested as replacements of glass fibers, obtaining noticeable tensile strengths, but being unable to reach the strength of glass fiber-reinforced composites. In this paper, polyamide 6 is proposed as a matrix for cellulosic fiber-based composites. A variety of fibers were tensile tested, in order to evaluate the creation of a strong interphase. The results show that, with a bleached hardwood fiber-reinforced polyamide 6 composite, it is possible to obtain tensile strengths higher than glass-fiber-reinforced polyolefin. The obtained composites show the existence of a strong interphase, allowing us to take advantage of the strengthening capabilities of such cellulosic reinforcements. These materials show advantageous mechanical properties, while being recyclable and partially renewable.

| S-EPMC7284898 | biostudies-literature

Enhancing thermoelectric properties of organic composites through hierarchical nanostructures.

Project description:Organic thermoelectric (TE) materials are very attractive due to easy processing, material abundance, and environmentally-benign characteristics, but their potential is significantly restricted by the inferior thermoelectric properties. In this work, noncovalently functionalized graphene with fullerene by ?-? stacking in a liquid-liquid interface was integrated into poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate). Graphene helps to improve electrical conductivity while fullerene enhances the Seebeck coefficient and hinders thermal conductivity, resulting in the synergistic effect on enhancing thermoelectric properties. With the integration of nanohybrids, the electrical conductivity increased from ~10,000 to ~70,000?S/m, the thermal conductivity changed from 0.2 to 2?W·K(-1)m(-1) while the Seebeck coefficient was enhanced by around 4-fold. As a result, nanohybrids-based polymer composites demonstrated the figure of merit (ZT) as high as 6.7 × 10(-2), indicating an enhancement of more than one order of magnitude in comparison to single-phase filler-based polymer composites with ZT at the level of 10(-3).

| S-EPMC3861799 | biostudies-other

Hierarchical Composites to Reduce N-Nitrosamines in Cigarette Smoke.

Project description:In order to reduce the harmful constituents in cigarette smoke, two hierarchical composites were synthesized. Based on, zeolites HZSM-5 or NaY fragments were introduced into the synthetic system of mesoporous silica SBA-15 or MCM-41 and assembled with the mesoporous materials. These porous composites combine the advantages of micro- and mesoporous materials, and exhibit higher effects than activated carbon on reducing tobacco specific nitrosamines (TSNA) and some vapor phase compounds in smoke.

| S-EPMC5455443 | biostudies-other

Facile Preparation of Self-Standing Hierarchical Porous Nitrogen-Doped Carbon Fibers for Supercapacitors from Plant Protein-Lignin Electrospun Fibers.

Project description:This research aims to develop self-standing nitrogen-doped carbon fiber networks from plant protein-lignin electrospun fibrous mats for supercapacitors. The challenge in preparing carbon fiber from protein is to maintain a fibrous structure during carbonization process. Thus, lignin was incorporated with protein. At protein-to-lignin ratio of 50:50 to 20:80, the electrospun fibers maintained their structure after carbonization and formed self-standing carbon fiber mats. Stacked graphene layer structure was developed in the carbon fibers at a relatively low carbonization temperature (<1000 °C) without the use of catalysts, which might be derived from both lignin and protein. Graphene layer structure conferred the carbon fibers with superior conductivity. The optimized carbon fiber networks possessed excellent capacitance performance in 6 M KOH of 410 F/g at 1 A/g and good cyclic stability. Such good electrochemical properties were due to the well-engineered characteristics of the materials, including a hierarchical porous texture, heteroatoms (nitrogen and oxygen), and the stacked graphene layer structure. This research not only has provided a convenient way to develop carbon fibers from plant protein-lignin for N-doped supercapacitor electrodes, but also opportunity to add value to plant proteins and lignin as by-products of agricultural industry processing.

| S-EPMC6641454 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data