The ZrO₂ Formation in ZrB₂/SiC Composite Irradiated by Laser.
Ontology highlight
ABSTRACT:
SUBMITTER: Liu L
PROVIDER: S-EPMC5458866 | biostudies-other | 2015 Dec
REPOSITORIES: biostudies-other
Similar Datasets
Project description:This study assessed the sinterability and microstructure of ZrB2-SiC-TaN and ZrB2-TaN ceramics. Spark plasma sintering at 2000 °C and 30 MPa for 5 min produced both ceramics. The relative density of ZrB2 ceramic containing TaN was 95.3%; the addition of SiC increased this value to 98.1%. SiC's contribution to the elimination of ZrB2 surface oxides was the primary factor in the advancement of densification. The in situ formation of hexagonal boron nitride at the interface of TaN and ZrB2 was confirmed by high-resolution transmission electron microscopy, field emission-electron probe microanalyzer, X-ray diffractometry, and field emission scanning electron microscopy. Moreover, the in situ graphite might be produced as a byproduct of the SiC-SiO2 process, hence boosting the reduction of oxide compounds in the ternary system. The SiC compound had the highest hardness (29 ± 3 GPa), while the ZrB2/TaN interface exhibited the greatest values of elastic modulus (473 ± 26 GPa) and stiffness (0.76 ± 0.13 mN/nm).
| S-EPMC9374782 | biostudies-literature
Project description:BackgroundFracture or chipping are major concerning failures of an all-ceramic restoration. Repairing of the failure restoration using intra-oral technique is time saving and cost effective treatment modality. The present study was proposed to evaluate effect of Er,Cr:YSGG laser irradiation on shear bond strength between zirconia/porcelain and composite resin.MethodsThirty zirconia and thirty zirconia based porcelain disc shape specimens were prepared. Three different surface treatment procedure were applied the specimens. For control groups (Group ZC and PC), instruction manual of an intra-oral porcelain repair system was followed. Different pulse rates of Er,Cr:YSGG laser irradiation (short and long pulses) were applied to zirconia and porcelain surfaces for other groups (Group ZS, ZL, PS, and PL). Porcelain repair kit was used to repair specimens using standard cylindrical teflon mold (2 × 2 mm). Repair bond strength of the repaired specimens was tested using a universal testing machine.ResultsHighest mean bond strength value was observed at Group PC that was significantly higher than laser applied porcelain groups. Long pulse laser irradiation illustrated that increased mean bond strength compared to short pulse application on to the porcelain surface. Laser applied zirconia groups showed better mean bond strength than Group ZC, but differences between the groups were not statistically significant.ConclusionDifferent modes of Er,Cr:YSGG laser irradiation enhanced repair bond strength of the composite resin to zirconia, but these were not significant. Following the instruction manual for surface treatment on the porcelain surface was better method than Er,Cr:YSGG laser surface conditioning.
| S-EPMC6717752 | biostudies-literature
Project description:The capacity to synthesize and design highly intricated nanoscale objects of different sizes, surfaces, and shapes dramatically conditions the development of multifunctional nanomaterials. Ultrafast laser technology holds great promise as a contactless process able to rationally and rapidly manufacture complex nanostructures bringing innovative surface functions. The most critical challenge in controlling the growth of laser-induced structures below the light diffraction limit is the absence of external order associated to the inherent local interaction due to the self-organizing nature of the phenomenon. Here high aspect-ratio nanopatterns driven by near-field surface coupling and architectured by timely-controlled polarization pulse shaping are reported. Electromagnetic coupled with hydrodynamic simulations reveal why this unique optical manipulation allows peaks generation by inhomogeneous local absorption sustained by nanoscale convection. The obtained high aspect-ratio surface nanotopography is expected to prevent bacterial proliferation, and have great potential for catalysis, vacuum to deep UV photonics and sensing.
| S-EPMC9313481 | biostudies-literature
Project description:The aqueous dispersion behavior of ZrB₂, SiC powders with B₄C and C as sintering aids was investigated. Well co-dispersed suspension can be obtained in acidic solutions in presence of polyethyleneimine (PEI). The adsorption of PEI on the powder surface was measured by thermal gravimetric (TG) analysis. Rheological measurements displayed the effect of dispersant on the flow behavior of as-prepared slurries. An optimum condition was obtained with 1 wt % PEI. The viscosity of 40 vol % ZrB₂-SiC-B₄C-C (ZSBC) suspension at 100 s-1 was as low as 0.74 Pa·s, which was suitable for aqueous processing.
| S-EPMC5452644 | biostudies-other
Project description:This work aims at studying the effect of the milling conditions on the microstructure and mechanical properties of a ZrB₂-5 vol% Si₃N₄ matrix reinforced with chopped Hi-Nicalon SiC fibers. Several composites were obtained using different milling conditions in terms of time, speed and type of milling media. The composites were prepared from commercial powders, ball milled, dried and shaped, and hot pressed at 1720 °C. Their relative bulk densities achieved values as high as 99%. For each material the fiber length distribution, the extent of reacted fiber area and matrix mean grain size were evaluated in order to ascertain the effects of milling time, milling speed and type of milling media. While the fracture toughness and hardness were statistically the same independently of the milling conditions, the flexural strength changed. From the results obtained, the best milling conditions for optimized mechanical properties were determined.
| S-EPMC5452501 | biostudies-other
Project description:Preliminary characterization of the microstructure of Al/SiCp composites prepared by Laser Metal Deposition (LMD) was analyzed, and the microhardness and wear behavior of the materials manufactured have been evaluated. It has been determined that the combined effect of the laser speed and power is decisive for the fabrication process. The microstructure characterization shows that the presence of hygroscopic Al4C3 can be avoided by adding Ti to the composite matrix. The wear behavior of the LMD samples and their microhardness have been compared with Powder Metallurgy samples with the same composition. The LMD samples showed higher hardness and wear resistance.
| S-EPMC7435613 | biostudies-literature
Project description:Displaying a full or tuneable emission spectrum with highly efficient is significant for luminescent materials used in solid-state lighting. Silicon carbide (SiC) has potential for use in photoelectric devices that operate under extreme conditions. In this paper, we present a method to selectively modify the photoluminescence (PL) properties of SiC by ultrafast laser direct writing. Based on this method, visible white PL could be observed by the naked eye at room temperature under ultraviolet excitation. By increasing the laser power intensity from 40 to 80 MW/cm2, the PL of the irradiated samples increased and pure white sunlight-like emission with controlled colour temperature was realised. The optimised laser power intensity of 65 MW/cm2 achieved a desirable colour temperature similar to that of sunlight (x = 0.33, y = 0.33 and colour temperature of 5500 K) and suppressed blue emission. By direct laser irradiation along designed scanning path, a large-scale and arbitrary pattern white emission was fabricated. The origin of the white luminescence was a mixture of multiple luminescent transitions of oxygen-related centres that turned the Si-C system into silicon oxycarbide. This work sheds light on new luminescent materials and a preparation technique for next-generation lighting devices.
| S-EPMC5762700 | biostudies-literature
Project description:The formation of superconducting nanocomposites from preformed nanocrystals is still not well understood. Here, we examine the case of ZrO? nanocrystals in a YBa?Cu?O7−x matrix. First we analyzed the preformed ZrO? nanocrystals via atomic pair distribution function analysis and found that the nanocrystals have a distorted tetragonal crystal structure. Second, we investigated the influence of various surface ligands attached to the ZrO? nanocrystals on the distribution of metal ions in the pyrolyzed matrix via secondary ion mass spectroscopy technique. The choice of stabilizing ligand is crucial in order to obtain good superconducting nanocomposite films with vortex pinning. Short, carboxylate based ligands lead to poor superconducting properties due to the inhomogeneity of metal content in the pyrolyzed matrix. Counter-intuitively, a phosphonate ligand with long chains does not disturb the growth of YBa?Cu?O7−x. Even more surprisingly, bisphosphonate polymeric ligands provide good colloidal stability in solution but do not prevent coagulation in the final film, resulting in poor pinning. These results thus shed light on the various stages of the superconducting nanocomposite formation.
| S-EPMC6073135 | biostudies-literature
Project description:A new approach for the stabilization of the ferroelectric orthorhombic ZrO2 films is demonstrated through nanosecond laser annealing (NLA) of as-deposited Si/SiOx /W(14 nm)/ZrO2 (8 nm)/W(22 nm), grown by ion beam sputtering at low temperatures. The NLA process optimization is guided by COMSOL multiphysics simulations. The films annealed under the optimized conditions reveal the presence of the orthorhombic phase, as confirmed by X-ray diffraction, electron backscatter diffraction, and transmission electron microscopy. Macroscopic polarization-electric field hysteresis loops show ferroelectric behavior, with saturation polarization of 12.8 µC cm-2 , remnant polarization of 12.7 µC cm-2 and coercive field of 1.2 MV cm-1 . The films exhibit a wake-up effect that is attributed to the migration of point defects, such as oxygen vacancies, and/or a transition from nonferroelectric (monoclinic and tetragonal phase) to the ferroelectric orthorhombic phase. The capacitors demonstrate a stable polarization with an endurance of 6.0 × 105 cycles, demonstrating the potential of the NLA process for the fabrication of ferroelectric memory devices with high polarization, low coercive field, and high cycling stability.
| S-EPMC10214231 | biostudies-literature
Project description:High-temperature plasma irradiation of materials leads to significant modification of surface structure, growth of deposited composite films and surface layers with induced self-similar granularity on the scale from macroscales to nanoscale due to strong plasma-surface interaction. The aim of this study was to characterize lithium materials irradiated with high-temperature plasma in the T-10 tokamak and PLM device. The reactivity of lithium leads to reactions with impurities in the plasma and on the vessel. Post-mortem analyses by the X-ray photoemission spectroscopy and X-ray analysis have been used to identify deposits composition and morphology. Lithium carbonate composites have been detected by analysis demonstrating materials mixing and evidence of plasma-induced structure. New structures with the high specific surface area of hierarchical granular are registered. The reference industrial powder of lithium carbonate irradiated with steady-state plasma in the PLM device has acquired a new similar structure demonstrating universal influence of plasma on the structure of irradiated materials.
| S-EPMC7677702 | biostudies-literature