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Synthesis of vinyl boronates from aldehydes by a practical boron-Wittig reaction.

ABSTRACT: A highly stereoselective boron-Wittig reaction between stable and readily accessible 1,1-bis(pinacolboronates) and aldehydes furnishes a variety of synthetically useful di- and trisubstituted vinyl boronate esters.

SUBMITTER: Coombs JR

PROVIDER: S-EPMC5510876 | biostudies-other | 2015 Apr

REPOSITORIES: biostudies-other

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Synthesis of vinyl boronates from aldehydes by a practical boron-Wittig reaction.

Coombs John R JR Zhang Liang L Morken James P JP

Organic letters 20150323 7

A highly stereoselective boron-Wittig reaction between stable and readily accessible 1,1-bis(pinacolboronates) and aldehydes furnishes a variety of synthetically useful di- and trisubstituted vinyl boronate esters. ...[more]

PMID: 25799147

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