Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Recycling of Pre-Washed Municipal Solid Waste Incinerator Fly Ash in the Manufacturing of Low Temperature Setting Geopolymer Materials.

ABSTRACT: In this work, three samples of municipal solid waste incinerators fly ash (MSWI-FA) have been stabilized in systems containing coal fly ash to create geopolymers through a polycondensation reaction. Monolithic products have been obtained with both MSWI fly ash as received and after the partial removal of chloride and sulfate by water washing. The polycondensation products have been characterized qualitatively by means of Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy and quantitatively, through the determination of the volume of reacted water and silicate. Furthermore, the heavy metals and chloride releases together with the physico-mechanical properties have been evaluated on the hardened products. In conclusion, considering the technological and environmental performances of the obtained geopolymers, they could be suitable for many non-structural applications, such as backfilling of abandoned quarries, decorative materials or brick fireplaces, hearths, patios, etc.

SUBMITTER: Ferone C

PROVIDER: S-EPMC5521313 | biostudies-other | 2013 Aug

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Similar Datasets

Electrokinetic remediation of heavy metals from municipal solid waste incineration fly ash pretreated by nitric acid.

Project description:Municipal solid waste incineration (MSWI) fly ash has a high concentration of heavy metals (HMs) which are hazardous to the environment. Moreover, it has high pH and buffering capacity which hinders the removal of HMs. Another constraining factor is the considerable fraction of HMs which exist in oxidizable and reducible states. The acid pretreatment of MSWI fly ash is a key solution to this problem. Therefore, the current experiment is carried out to evaluate the effect of acid pretreatment of MSWI fly ash and reaction/proposed time on the removal efficiency of HMs through an electrokinetic experiment. The leaching experiment results show that acid pretreatment has increased the desorption/release of heavy metal ions (Pb2+, Cd2+, Cu2+ and Zn2+). It enhances the migration of HM ions in electrolytic cells which get precipitated at the cathode, thereby increasing the removal efficiency of HMs in the electrokinetic experiment. Moreover, it is found that prolonged proposed time (12 d) has significant effect on the removal efficiency of HMs. Finally, it is concluded that acid pretreatment and prolonged proposed time have enhanced the removal electrokinetic remediation of HMs which is carried out via three processes, i.e. desorption (enhanced by acidification), migration and precipitation.

| S-EPMC6124067 | biostudies-literature

Microbial induced solidification and stabilization of municipal solid waste incineration fly ash with high alkalinity and heavy metal toxicity.

Project description:This paper presents an experimental study on the applicability of microbial induced carbonate precipitation (MICP) to treat municipal solid waste incineration (MSWI) fly ash with high alkalinity and heavy metal toxicity. The experiments were carried out on fly ashes A and B produced from incineration processes of mechanical grate furnace and circulating fluidized bed, respectively. The results showed that both types of fly ashes contained high CaO content, which could supply sufficient endogenous Ca for MICP treatment. Moreover, S. pasteurii can survive from high alkalinity and heavy metal toxicity of fly ash solution. Further, the unconfined compressive strength (UCS) of MICP treated fly ashes A and B reached 0.385MPa and 0.709 MPa, respectively. The MICP treatment also resulted in a reduction in the leaching toxicity of heavy metals, especially for Cu, Pb and Hg. MICP had a higher solidification and stabilization effect on fly ash B, which has finer particle size and higher Ca content. These findings shone a light on the possibility of using MICP technique as a suitable and efficient tool to treat the MSWI fly ash.

| S-EPMC6797113 | biostudies-literature

Experimental study on removing heavy metals from the municipal solid waste incineration fly ash with the modified electrokinetic remediation device.

Project description:The MSWI fly ash which contains a large number of heavy metal substances is a subsidiary product of waste incineration power generation technology. If the MSWI fly ash is disposed improperly, heavy metal pollutants will pose a great threat to environmental safety and human health. Based on the technology of electrokinetic remediation, the feasibility of removing heavy metal pollutants from the MSWI fly ash using a modified electrokinetic remediation device - cylinder device was evaluated in this study. Differing from the traditional cuboid device with the volume ratio of the cathode chamber to the anode chamber being 1:1, the volume ratio of the cathode chamber to the anode chamber of the cylinder device was 16:1. Changes in parameters, such as pH values and conductivity in the cathode and the anode chambers as well as current and voltage in the sample area were analysed under the voltage gradient of 2?V/cm. After the experiment, the average removal efficiencies for Zn, Pb, Cd and Cu in the sample area were 53.2%, 31.4%, 42.3% and 30.7%, respectively. It indicates that the cylinder device is effective in removing heavy metals from the MSWI fly ash. Adopting the cylinder device for the experimental study on the electrokinetic remediation technology could provide a better way of thinking for the future engineering practices and applications.

| S-EPMC6547674 | biostudies-literature

Rice Husk Ash to Stabilize Heavy Metals Contained in Municipal Solid Waste Incineration Fly Ash: First Results by Applying New Pre-treatment Technology.

Project description:A new technology was recently developed for municipal solid waste incineration (MSWI) fly ash stabilization, based on the employment of all waste and byproduct materials. In particular, the proposed method is based on the use of amorphous silica contained in rice husk ash (RHA), an agricultural byproduct material (COSMOS-RICE project). The obtained final inert can be applied in several applications to produce "green composites". In this work, for the first time, a process for pre-treatment of rice husk, before its use in the stabilization of heavy metals, based on the employment of Instant Pressure Drop technology (DIC) was tested. The aim of this work is to verify the influence of the pre-treatment on the efficiency on heavy metals stabilization in the COSMOS-RICE technology. DIC technique is based on a thermomechanical effect induced by an abrupt transition from high steam pressure to a vacuum, to produce changes in the material. Two different DIC pre-treatments were selected and thermal annealing at different temperatures were performed on rice husk. The resulting RHAs were employed to obtain COSMOS-RICE samples, and the stabilization procedure was tested on the MSWI fly ash. In the frame of this work, some thermal treatments were also realized in O2-limiting conditions, to test the effect of charcoal obtained from RHA on the stabilization procedure. The results of this work show that the application of DIC technology into existing treatment cycles of some waste materials should be investigated in more details to offer the possibility to stabilize and reuse waste.

| S-EPMC5455375 | biostudies-other

Effect of Mass Proportion of Municipal Solid Waste Incinerator Bottom Ash Layer to Municipal Solid Waste Layer on the Cu and Zn Discharge from Landfill.

Project description:Municipal solid waste incinerator (MSWI) bottom ash is often used as the protection layer for the geomembrane and intermediate layer in the landfill. In this study, three sets of simulated landfills with different mass proportion of MSWI bottom ash layer to municipal solid waste (MSW) layer were operated. Cu and Zn concentrations in the leachates and MSW were monitored to investigate the effect of MSWI bottom ash layer on the Cu and Zn discharge from the landfill. The results showed that the Zn discharge was dependent on the mass proportion of MSWI bottom ash layer. The pH of landfill was not notably increased when the mass proportion of MSWI bottom ash layer to MSW layer was 1?:?9, resulting in the enhancement of the Zn discharge. However, Zn discharge was mitigated when the mass proportion was 2?:?8, as the pH of landfill was notably promoted. The discharge of Cu was not dependent on the mass proportion, due to the great affinity of Cu to organic matter. Moreover, Cu and Zn contents of the sub-MSW layer increased due to the MSWI bottom ash layer. Therefore, the MSWI bottom ash layer can increase the potential environmental threat of the landfill.

| S-EPMC5156799 | biostudies-literature

Life Cycle Assessment and Impact Correlation Analysis of Fly Ash Geopolymer Concrete.

Project description:Geopolymer concrete (GPC) has drawn widespread attention as a universally accepted ideal green material to improve environmental conditions in recent years. The present study systematically quantifies and compares the environmental impact of fly ash GPC and ordinary Portland cement (OPC) concrete under different strength grades by conducting life cycle assessment (LCA). The alkali activator solution to fly ash ratio (S/F), sodium hydroxide concentration (CNaOH), and sodium silicate to sodium hydroxide ratio (SS/SH) were further used as three key parameters to consider their sensitivity to strength and CO2 emissions. The correlation and influence rules were analyzed by Multivariate Analysis of Variance (MANOVA) and Gray Relational Analysis (GRA). The results indicated that the CO2 emission of GPC can be reduced by 62.73%, and the correlation between CO2 emission and compressive strength is not significant for GPC. The degree of influence of the three factors on the compressive strength is CNaOH (66.5%) > SS/SH (20.7%) > S/F (9%) and on CO2 emissions is S/F (87.2%) > SS/SH (10.3%) > CNaOH (2.4%). Fly ash GPC effectively controls the environmental deterioration without compromising its compressive strength; in fact, it even in favor.

| S-EPMC8658180 | biostudies-literature

Influence of Waste Glass Particle Size on the Physico-Mechanical Properties and Porosity of Foamed Geopolymer Composites Based on Coal Fly Ash.

Project description:In order to protect the environment and counteract climate change, it is necessary to take any actions that enable a reduction in CO2 emissions. One of the key areas is research focused on developing alternative sustainable materials for construction to reduce the global demand for cement. This work presents the properties of foamed geopolymers with the addition of waste glass as well as determined the optimal size and amount of waste glass for improving the mechanical and physical features of the produced composites. Several geopolymer mixtures were fabricated by replacing coal fly ash with 0%, 10%, 20%, and 30% of waste glass by weight. Moreover, the effect of using different particle size ranges of the addition (0.1-1200 µm; 200-1200 µm; 100-250 µm; 63-120 µm; 40-63 µm; 0.1-40 µm) in the geopolymer matrix was examined. Based on the results, it was found that the application of 20-30% of waste glass with a particle size range of 0.1-1200 µm and a mean diameter of 550 µm resulted in approximately 80% higher compressive strength in comparison to unmodified material. Moreover, the samples produced using the smallest fraction (0.1-40 µm) of waste glass in the amount of 30% reached the highest specific surface area (43.711 m2/g), maximum porosity (69%), and density of 0.6 g/cm3.

| S-EPMC10004531 | biostudies-literature

Test study on mechanical properties of compound municipal solid waste incinerator bottom ash premixed fluidized solidified soil.

Project description:In this paper, the municipal solid waste incineration bottom ash (MSW-IBA) is used as the fine aggregate and firming agent component of the premixed fluid stabilized soil (PFSS). Through the mechanical strength test, and the hydration products and microstructure characterization, the effects of the NaOH content for MSW-IBA pre-aging treatment and activator content on the mechanical properties of the PFSS are studied. The results show that the mechanical strength of the prepared PFSS is closely related to the amount of NaOH and the activator. The increase in the amount of NaOH and activator can affect the formation of early hydration product Aft, and reduce the early strength. However, it can promote the depolymerization of glass phase in MSW-IBA and slag to form C-(A)-S-H and Mg-(A)-S-H gel, increase the microstructure density, and thus improve the late strength. The application of MSW-IBA in PFSS can achieve the recycling of solid waste.

| S-EPMC10484961 | biostudies-literature

Influence of Activators on Mechanical Properties of Modified Fly Ash Based Geopolymer Mortars.

Project description:The aim of this work was to study the influence of the type of activator on the formulation of modified fly ash based geopolymer mortars. Geopolymer and alkali-activated materials (AAM) were made from fly ashes derived from coal and biomass combustion in thermal power plants. Basic activators (NaOH, CaO, and Na2SiO3) were mixed with fly ashes in order to develop binding properties other than those resulting from the use of Portland cement. The results showed that the mortars with 5 mol/dm3 of NaOH and 100 g of Na2SiO3 (N5-S22) gave a greater compressive strength than other mixes. The compressive strengths of analyzed fly ash mortars with activators N5-S22 and N5-C10 (5 mol/dm3 NaOH and 10% CaO) varied from 14.3 MPa to 5.9 MPa. The better properties of alkali-activated mortars with regular fly ash were influenced by a larger amount of amorphous silica and alumina phases. Scanning electron microscopy and calorimetry analysis provided a better understanding of the observed mechanisms.

| S-EPMC7084247 | biostudies-literature

A Bibliometric Analysis of Research Progress and Trends on Fly Ash-Based Geopolymer.

Project description:The objective of this work is to present the research progress and applications of fly ash-based geopolymer, and summarize the future research hotpots. Since 1998, scholars have made important contributions to the study of fly ash-based geopolymer, and a large number of research studies have been published. Therefore, a bibliometric analysis for the determination of the research status, trend, and history of fly ash-based geopolymer was conducted in the present study. A total of 4352 publications on fly ash-based geopolymer were collected between 1998 and 2022, with an increasing trend year by year. China and Australia are the largest contributors to the field, and the research institutions in each country cooperate closely. In addition, the most contributing research areas are MATERIALS SCIENCE, ENGINEERING, and CONSTRUCTION & BUILDING TECHNOLOGY. The keywords including fly ash, compressive strength, and mechanical property are the most frequently appearing words. On the whole, the development of fly ash-based geopolymer could be divided into three stages including the replacement of ordinary Portland cement, the development of multifunctional materials, and the reduction of environmental impact by the conversion of solid waste. This overview could provide an important guidance for the development of fly ash-based geopolymer.

| S-EPMC9324275 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data