Dataset Information

Chemically Modified Polyvinyl Chloride for Removal of Thionine Dye (Lauth's Violet).

ABSTRACT: The chemical modification of hydrophobic polymer matrices is an alternative way to elchange their surface properties. The introduction of sulfonic groups in the polymer changes the surface properties such as adhesion, wettability, catalytic ability, and adsorption capacity. This work describes the production and application of chemically modified polyvinyl chloride (PVC) as adsorbent for dyes removal. Chemical modification of PVC was evaluated by infrared spectroscopy and elemental analysis, which indicated the presence of sulfonic groups on PVC. The chemically modified PVC (PVCDS) showed an ion exchange capacity of 1.03 mmol-1, and efficiently removed the thionine dye (Lauth's violet) from aqueous solutions, reaching equilibrium in 30 min. The adsorption kinetics was better adjusted for a pseudo second order model. This result indicates that the adsorption of thionine onto PVCDS occurs by chemisorption. Among the models for the state of equilibrium, SIPS and Langmuir exhibited the best fit to the experimental results and PVCDS showed high adsorption capacities (370 mg-1). Thus, it is assumed that the system presents homogeneous characteristics to the distribution of active sites. The modification promoted the formation of surface characteristics favorable to the dye adsorption by the polymer.

SUBMITTER: Ali HMAMMS

PROVIDER: S-EPMC5706245 | biostudies-other | 2017 Nov

REPOSITORIES: biostudies-other

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Chemically Modified Polyvinyl Chloride for Removal of Thionine Dye (Lauth's Violet).

Ali Helena Ma A M M S HMAMMS Silva Cleuzilene V CV Royer Betina B Rodrigues Filho Guimes G Cerqueira Daniel A DA Assunção Rosana M N RMN

Materials (Basel, Switzerland) 20171112 11

The chemical modification of hydrophobic polymer matrices is an alternative way to elchange their surface properties. The introduction of sulfonic groups in the polymer changes the surface properties such as adhesion, wettability, catalytic ability, and adsorption capacity. This work describes the production and application of chemically modified polyvinyl chloride (PVC) as adsorbent for dyes removal. Chemical modification of PVC was evaluated by infrared spectroscopy and elemental analysis, whi ...[more]

PMID: 29137158

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Project description:In this study, a novel PVA/SA/ZSM-5 zeolite membrane with good regeneration capacity was successfully prepared by solvent casting technique. The properties of the membranes were assessed by employing different characterization techniques such as X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), optical microscopy (OP), thermogravimetric analysis (TGA), contact angle and universal testing machine (UTM). XRD, TGA and UTM results revealed that the crystallinity and thermo-mechanical performance of the membrane could be tuned with zeolite content. The successful incorporation of zeolite into the polymer matrix was confirmed by FT-IR, SEM and OP analysis. The adsorption ability of the as-prepared membrane was evaluated with a model anionic dye, Congo red. Adsorption studies show that the removal efficiency of the membrane could be tuned by varying zeolite content, initial concentration of dye, contact time, pH and temperature. Maximum dye adsorption (5.33 mg/g) was observed for 2.5 wt% zeolite loaded membrane, at an initial dye concentration of 10 ppm, pH 3 and temperature 30 °C. The antibacterial efficiency of the membrane against gram-positive (Staphylococcus aureus) and gram-negative bacteria (Escherichia coli) was also reported. The results show that membrane inhibits the growth of both gram-positive and gram-negative bacteria. The adsorption isotherm was studied using two models: Langmuir and Freundlich isotherm. The results show that the experimental data fitted well with Freundlich isotherm with a high correlation coefficient (R2 = 0.998). Meanwhile, the kinetic studies demonstrate that pseudo-second-order (R2 = 0.999) model describe the adsorption of Congo red onto PVA/SA/ZSM-5 zeolite membrane better than pseudo-first-order (R2 = 0.972) and intra particle diffusion model (R2 = 0.91). The experimental studies thus suggest that PVA/SA/ZSM-5 zeolite could be a promising candidate for the removal of Congo red from aqueous solution.

Dataset Information

Chemically Modified Polyvinyl Chloride for Removal of Thionine Dye (Lauth's Violet).

Publications

Chemically Modified Polyvinyl Chloride for Removal of Thionine Dye (Lauth's Violet).

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