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Quantum confined peptide assemblies with tunable visible to near-infrared spectral range.

ABSTRACT: Quantum confined materials have been extensively studied for photoluminescent applications. Due to intrinsic limitations of low biocompatibility and challenging modulation, the utilization of conventional inorganic quantum confined photoluminescent materials in bio-imaging and bio-machine interface faces critical restrictions. Here, we present aromatic cyclo-dipeptides that dimerize into quantum dots, which serve as building blocks to further self-assemble into quantum confined supramolecular structures with diverse morphologies and photoluminescence properties. Especially, the emission can be tuned from the visible region to the near-infrared region (420?nm to 820?nm) by modulating the self-assembly process. Moreover, no obvious cytotoxic effect is observed for these nanostructures, and their utilization for in vivo imaging and as phosphors for light-emitting diodes is demonstrated. The data reveal that the morphologies and optical properties of the aromatic cyclo-dipeptide self-assemblies can be tuned, making them potential candidates for supramolecular quantum confined materials providing biocompatible alternatives for broad biomedical and opto-electric applications.

SUBMITTER: Tao K

PROVIDER: S-EPMC6089888 | biostudies-other | 2018 Aug

REPOSITORIES: biostudies-other

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Quantum confined peptide assemblies with tunable visible to near-infrared spectral range.

Tao Kai K Fan Zhen Z Sun Leming L Makam Pandeeswar P Tian Zhen Z Ruegsegger Mark M Shaham-Niv Shira S Hansford Derek D Aizen Ruth R Pan Zui Z Galster Scott S Ma Jianjie J Yuan Fan F Si Mingsu M Qu Songnan S Zhang Mingjun M Gazit Ehud E Li Junbai J

Nature communications 20180813 1

Quantum confined materials have been extensively studied for photoluminescent applications. Due to intrinsic limitations of low biocompatibility and challenging modulation, the utilization of conventional inorganic quantum confined photoluminescent materials in bio-imaging and bio-machine interface faces critical restrictions. Here, we present aromatic cyclo-dipeptides that dimerize into quantum dots, which serve as building blocks to further self-assemble into quantum confined supramolecular st ...[more]

PMID: 30104564

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Project description:Quartz is the most abundant mineral on the earth's surface. It is spectrally active in the longwave infrared (LWIR) region with no significant spectral features in the optical domain, i.e., visible-near-infrared-shortwave-infrared (Vis-NIR-SWIR) region. Several space agencies are planning to mount optical image spectrometers in space, with one of their missions being to map raw materials. However, these sensors are active across the optical region, making the spectral identification of quartz mineral problematic. This study demonstrates that indirect relationships between the optical and LWIR regions (where quartz is spectrally dominant) can be used to assess quartz content spectrally using solely the optical region. To achieve this, we made use of the legacy Israeli soil spectral library, which characterizes arid and semiarid soils through comprehensive chemical and mineral analyses along with spectral measurements across the Vis-NIR-SWIR region (reflectance) and LWIR region (emissivity). Recently, a Soil Quartz Clay Mineral Index (SQCMI) was developed using mineral-related emissivity features to determine the content of quartz, relative to clay minerals, in the soil. The SQCMI was highly and significantly correlated with the Vis-NIR-SWIR spectral region (R2 = 0.82, root mean square error (RMSE) = 0.01, ratio of performance to deviation (RPD) = 2.34), whereas direct estimation of the quartz content using a gradient-boosting algorithm against the Vis-NIR-SWIR region provided poor results (R2 = 0.45, RMSE = 15.63, RPD = 1.32). Moreover, estimation of the SQCMI value was even more accurate when only the 2000-2450 nm spectral range (atmospheric window) was used (R2 = 0.9, RMSE = 0.005, RPD = 1.95). These results suggest that reflectance data across the 2000-2450 nm spectral region can be used to estimate quartz content, relative to clay minerals in the soil satisfactorily using hyperspectral remote sensing means.

Dataset Information

Quantum confined peptide assemblies with tunable visible to near-infrared spectral range.

Publications

Quantum confined peptide assemblies with tunable visible to near-infrared spectral range.

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