Ontology highlight
ABSTRACT:
SUBMITTER: Martinez-Ferrate O
PROVIDER: S-EPMC6220868 | biostudies-other | 2018 Oct
REPOSITORIES: biostudies-other
Martínez-Ferraté Oriol O Werlé Christophe C Franciò Giancarlo G Leitner Walter W
ChemCatChem 20181011 20
A catalytic system based on complexes comprising abundant and cheap manganese together with readily available aminotriazole ligands is reported. The new Mn(I) complexes are catalytically competent in transfer hydrogenation of ketones with 2-propanol as hydrogen source. The reaction proceeds under mild conditions at 80 °C for 20 h with 3 % of catalyst loading using either KO <sup><i>t</i></sup> Bu or NaOH as base. Good to excellent yields were obtained for a wide substrate scope with broad functi ...[more]