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Green-chemistry Compatible Approach to TiO2-supported PdAu Bimetallic Nanoparticles for Solvent-free 1-Phenylethanol Oxidation under Mild Conditions.

ABSTRACT: TiO2-supported PdAu bimetallic nanoparticles (NPs) with small size and good dispersity were prepared by the room-temperature ionic liquid-assisted bimetal sputtering, which is simple, environmentally friendly, and free of additives and byproducts. Pd/Au atomic ratio can be tuned by controlling the sputtering conditions simply. High catalytic activity was found in PdAu-NPs-TiO2 hybrids for solvent-free selective oxidation of 1-phenylethanol using O2 as the oxidant at the low temperature of 50 °C and low pressure of 1 atm. It was found that Pd/Au ratio strongly affected the catalytical activity, and the highest conversion of about 35 % and turnover frequency of about 421 h-1 were achieved at 1:1 of Pd/Au atomic ratio. The synergistic effect in PdAu NPs was also discussed based on the comprehensive characterization results. The present approach may offer an alternative platform for future development of green-chemistry compatible bimetallic nanocatalysts.

SUBMITTER: Chang JB 

PROVIDER: S-EPMC6223906 | biostudies-other | 2015

REPOSITORIES: biostudies-other

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Green-chemistry Compatible Approach to TiO<sub>2</sub>-supported PdAu Bimetallic Nanoparticles for Solvent-free 1-Phenylethanol Oxidation under Mild Conditions.

Chang Jian-Bing JB   Liu Chang-Hai CH   Liu Jie J   Zhou Yu-Yan YY   Gao Xu X   Wang Sui-Dong SD  

Nano-micro letters 20150609 3

TiO<sub>2</sub>-supported PdAu bimetallic nanoparticles (NPs) with small size and good dispersity were prepared by the room-temperature ionic liquid-assisted bimetal sputtering, which is simple, environmentally friendly, and free of additives and byproducts. Pd/Au atomic ratio can be tuned by controlling the sputtering conditions simply. High catalytic activity was found in PdAu-NPs-TiO<sub>2</sub> hybrids for solvent-free selective oxidation of 1-phenylethanol using O<sub>2</sub> as the oxidant  ...[more]

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