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Non-Isothermal Oxidation Behavior and Mechanism of a High Temperature Near-? Titanium Alloy.

ABSTRACT: Non-isothermal oxidation is one of the important issues related to the safe application of high-temperature titanium alloys, so this study focuses on the non-isothermal oxidation behavior and mechanism of near-? titanium alloys. The thermogravimetry-differential scanning calorimetry (TGA/DSC) method was used to study the non-isothermal oxidation behavior of TA29 titanium alloy heated from room temperature to 1450 °C at a heating rate of 40 °C/min under pure oxygen atmosphere. The results show that non-isothermal oxidation behavior can be divided into five stages, including no oxidation, slow oxidation, accelerated oxidation, severe oxidation and deceleration oxidation; for the three-layer TiO? scale, Zr, Nb, Ta are enriched in the intermediate layer, while Al is rich in the inner layer and Sn is segregated at the oxide-substrate interface, which is related to their diffusion rates in the subsurface ? case. The oxidation mechanism for each stage is: oxygen barrier effect of a thin compact oxide film; oxygen dissolution; lattice transformation accelerating the dissolution and diffusion of oxygen; oxide formation; oxygen barrier effect of recrystallization and sintering microstructure in outer oxide scale. The alloying elements with high valence state and high diffusion rate in ?-Ti are favorable to slow down the oxidation rate at the stage governed by oxide formation.

SUBMITTER: Ouyang P

PROVIDER: S-EPMC6267292 | biostudies-other | 2018 Oct

REPOSITORIES: biostudies-other

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Non-Isothermal Oxidation Behavior and Mechanism of a High Temperature Near-α Titanium Alloy.

Ouyang Peixuan P Mi Guangbao G Li Peijie P He Liangju L Cao Jingxia J Huang Xu X

Materials (Basel, Switzerland) 20181030 11

Non-isothermal oxidation is one of the important issues related to the safe application of high-temperature titanium alloys, so this study focuses on the non-isothermal oxidation behavior and mechanism of near-α titanium alloys. The thermogravimetry-differential scanning calorimetry (TGA/DSC) method was used to study the non-isothermal oxidation behavior of TA29 titanium alloy heated from room temperature to 1450 °C at a heating rate of 40 °C/min under pure oxygen atmosphere. The results show th ...[more]

PMID: 30380791

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Project description:In this work, a near ?-type Ti5.1Al2.5Cr0.5Fe4.5Mo1.1Sn1.8Zr2.9Zn alloy was hot-rolled at the temperature of 800-880 °C with a thickness reduction of 87.5% and then heat-treated with the strategy of 880 °C/1 h/air cooling (AC) + 650 °C/3 h/AC. The microstructure difference between the hot-rolled and heat-treated titanium alloys and its influence on the ballistic impact behavior of the hot-rolled and heat-treated titanium alloys were analyzed. The microstructural investigation revealed that the average size of the acicular secondary ? phase (?s) dropped from 75 to 42 nm, and the corresponding amount of this phase increased significantly after heat treatment. In addition, the dislocation density of the ? and ? phases decreased from 0.3340 × 1015/m2 and 4.6746 × 1015/m2 for the hot-rolled titanium alloy plate to 0.2806 × 1015/m2 and 1.8050 × 1015/m2 for the heat-treated one, respectively. The high strength of the heat-treated titanium alloy was maintained, owing to the positive contribution of the acicular secondary ? phase. Furthermore, the critical fracture strain increased sharply from 19.9% for the hot-rolled titanium alloy plate to 23.1% for the heat-treated one, thereby overcoming (to some extent) the constraint of the strength-ductility trade-off. This is mainly attributed to the fact that the dislocation density and the difference between the dislocation densities of the ? and ? phases decreased substantially, and deformation localization was effectively suppressed after heat treatment. Damage to the hot-rolled and heat-treated titanium alloy plates after the penetration of a 7.62 mm ordinary steel core projectile at a distance of 100 m was assessed via industrial computer tomography and microstructure observation. The results revealed that a large crack (volume: 2.55 mm3) occurred on the rear face and propagated toward the interior of the hot-rolled titanium alloy plate. The crack tip was connected to a long adiabatic shear band with a depth of 3 mm along the thickness direction. However, good integrity of the heat-treated titanium alloy plate was maintained, owing to its excellent deformation capability. Ultimately, the failure mechanism of the hot-rolled and heat-treated titanium alloy plates was revealed by determining the crack-forming reasons in these materials.

Dataset Information

Non-Isothermal Oxidation Behavior and Mechanism of a High Temperature Near-? Titanium Alloy.

Publications

Non-Isothermal Oxidation Behavior and Mechanism of a High Temperature Near-α Titanium Alloy.

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