Ontology highlight
ABSTRACT:
SUBMITTER: Cruz P
PROVIDER: S-EPMC6401823 | biostudies-other | 2019 Jan
REPOSITORIES: biostudies-other
Cruz Paula P Fernandez-Bartolome Estefania E Cortijo Miguel M Delgado-Martínez Patricia P González-Prieto Rodrigo R Priego José L JL Torres M Rosario MR Jiménez-Aparicio Reyes R
Polymers 20190110 1
Herein, we describe the preparation of heteronuclear dirhodium-silver complexes by reaction between molecular Rh(II)-Rh(II) compounds [Rh₂(μ-O₂CR)₄L₂] (R = Me, Ph (<b>1</b>), CH₂OEt (<b>2</b>); L = solvent molecules) with paddlewheel structure and PPh₄[Ag(CN)₂]. One-dimensional coordination polymers of (PPh₄)<sub>n</sub>[Rh₂(μ-O₂CR)₄Ag(CN)₂]<sub>n</sub> (R = Me (<b>3</b>), Ph (<b>4</b>), CH₂OEt (<b>5</b>)) formula have been obtained by replacement of the two labile molecules in the axial positio ...[more]