Dataset Information

Use of Bacterial Cellulose and Crosslinked Cellulose Nanofibers Membranes for Removal of Oil from Oil-in-Water Emulsions.

ABSTRACT: Abstract: Never-dried bacterial cellulose (BC) and crosslinked cellulose nanofibers (CNF) were used for the removal of oil from stabilized and non-stabilized oil-in-water emulsions with droplet sizes less than 1 µm. The CNF membranes were exchanged with isopropyl alcohol before drying. The microscopic structure of the prepared membranes was evaluated using scanning electron microscopy (SEM); the water flux and the rejection of oil were evaluated using a dead-end filtration cell. BC harvested after different incubation time periods (2 to 10 days) did not show a change in the width of the nanofibers, but only the thickness of the membranes was increased. Pure water flux was not affected as a result of increasing thicknesses of BC membranes harvested after 4⁻10 days while BC harvested after two days had significantly higher water flux than the others. BC showed a higher flux and efficiency in removing oil from oil emulsions than CNF membranes. Removal of oil by the different membranes from the non-stabilized oil emulsion was more efficient than from the stabilized one.

SUBMITTER: Hassan E

PROVIDER: S-EPMC6418680 | biostudies-other | 2017 Aug

REPOSITORIES: biostudies-other

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Use of Bacterial Cellulose and Crosslinked Cellulose Nanofibers Membranes for Removal of Oil from Oil-in-Water Emulsions.

Hassan Enas E Hassan Mohammad M Abou-Zeid Ragab R Berglund Linn L Oksman Kristiina K

Polymers 20170823 9

<b>Abstract</b>: Never-dried bacterial cellulose (BC) and crosslinked cellulose nanofibers (CNF) were used for the removal of oil from stabilized and non-stabilized oil-in-water emulsions with droplet sizes less than 1 µm. The CNF membranes were exchanged with isopropyl alcohol before drying. The microscopic structure of the prepared membranes was evaluated using scanning electron microscopy (SEM); the water flux and the rejection of oil were evaluated using a dead-end filtration cell. BC harves ...[more]

PMID: 30965688

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Project description:Liquid-infused membranes have been introduced to membrane technology recently. The infusion liquid can be expelled, opening the pore, in response to an immiscible feed liquid pressure. In the open state, the pore wall is still covered with the infusion liquid forming the so-called liquid-lined pores. Liquid lining is expected to give anti-fouling properties to these membranes. The pressure-responsive pores can be used for efficient sorting of fluids from a mixture based on interfacial tension. For example, in a two-phase mixture of immiscible liquids, the required liquid entry pressure is different for the constituent liquids. Here, we investigate the capability of liquid-infused membranes for selective permeation of the dispersed phase, that is, oil from an oil-in-water (O/W) emulsion. The separation experiments are conducted in a dead-end pressure-controlled filtration cell using liquid-infused and non-infused membranes. In order to permeate the dispersed phase, oil droplets should come in contact with the membrane surface which is accomplished here by gravity-driven creaming. Our results reveal that by setting the feed pressure between the entry pressure of oil and that of the surfactant solution, oil can be successfully permeated. For high concentrations of surfactants, water also permeated partly. The amount of water permeated through liquid-infused membranes is lower than that through non-infused membranes, caused by the corresponding interfacial tensions. The results suggest that the presence of the infusion liquid in the membrane gives rise to the formation of three-phase interfaces in the pore, namely, the interface between surfactant solution-oil (?12) and that between oil-infusion liquid (?23). Based on the interfacial energy contributions, the additional interface between oil and the infusion liquid gives rise to an increase in the liquid entry pressure for the surfactant solution based on the combined interfacial tension (?12 + ?23) leading to less water permeation.

Dataset Information

Use of Bacterial Cellulose and Crosslinked Cellulose Nanofibers Membranes for Removal of Oil from Oil-in-Water Emulsions.

Publications

Use of Bacterial Cellulose and Crosslinked Cellulose Nanofibers Membranes for Removal of Oil from Oil-in-Water Emulsions.

Similar Datasets

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