Dataset Information

Topography-Directed Hot-Water Super-Repellent Surfaces.

ABSTRACT: Natural and artificial super-repellent surfaces are frequently textured with pillar-based discrete structures rather than hole-based continuous ones because the former exhibits lower adhesion from the reduced length of the three-phase contact line. Counterintuitively, here, the unusual topographic effects are discovered on hot-water super-repellency where the continuous microcavity surface outperforms the discrete microneedle/micropillar surface. This anomaly arises from the different dependencies of liquid-repellency stability on the surface structure and water temperature in the two topographies. The unexpected wetting dynamics are interpreted by determining timescales for droplet evaporation, vapor condensation, and droplet bouncing. The associated heat transfer process is unique to the wetting states and remarkably distinct from each other in the two topographies. It is envisioned that hot-water super-repellent microcavity surfaces will be advantageous for a variety of applications, especially when both self-cleaning and thermal insulation are imperative, such as clothing for scald protection and digital microfluidics for exothermic reactions.

SUBMITTER: Zhu P

PROVIDER: S-EPMC6755536 | biostudies-other | 2019 Sep

REPOSITORIES: biostudies-other

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Topography-Directed Hot-Water Super-Repellent Surfaces.

Zhu Pingan P Chen Rifei R Wang Liqiu L

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20190730 18

Natural and artificial super-repellent surfaces are frequently textured with pillar-based discrete structures rather than hole-based continuous ones because the former exhibits lower adhesion from the reduced length of the three-phase contact line. Counterintuitively, here, the unusual topographic effects are discovered on hot-water super-repellency where the continuous microcavity surface outperforms the discrete microneedle/micropillar surface. This anomaly arises from the different dependenci ...[more]

PMID: 31559129

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Project description:Wetting plays a major role in the close interactions between liquids and solid surfaces, which can be tailored by modifying the chemistry as well as the structures of the surfaces' outermost layer. Several methodologies, such as chemical vapor deposition, physical vapor deposition, electroplating, and chemical reactions, among others, have been adopted for the alteration/modification of such interactions suitable for various applications. However, the fabrication of low-contact line-pinning hydrophobic surfaces via simple and easy methods remains an open challenge. In this work, we exploit one-step and multiple-step silicone oil (5-100 cSt) grafting on smooth silicon substrates (although the technique is suitable for other substrates), looking closely at the effect of viscosity as well as the volume and layers (one to five) of oil grafted as a function of the deposition method. Remarkably, the optimization of grafting of silicone oil fabrication results in non-wetting surfaces with extremely low contact angle hysteresis (CAH) below 1° and high contact angles (CAs) of ∼108° after a single grafting step, which is an order of magnitude smaller than the reported values of previous works on silicone oil-grafted surfaces. Moreover, the different droplet-surface interactions and pinning behavior can additionally be tailored to the specific application with CAH ranging from 1 to 20° and sliding angles between 1.5 and 60° (for droplet volumes of 3 μL), depending on the fabrication parameters adopted. In terms of roughness, all the samples (independent of the grafting parameters) showed small changes in the root-mean-square roughness below 20 nm. Lastly, stability analysis of the grafting method reported here under various conditions shows that the coating is quite stable under mechanical vibrations (bath ultrasonication) and in a chemical environment (ultrasonication in a bath of ethanol) but loses its low-pinning characteristics when exposed to saturated steam at T ∼ 99 °C. The findings presented here provide a basis for selecting the most appropriate and suitable method and parameters for silicone oil grafting aimed at low pinning and low hysteresis surfaces for specific applications.

Dataset Information

Topography-Directed Hot-Water Super-Repellent Surfaces.

Publications

Topography-Directed Hot-Water Super-Repellent Surfaces.

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