Not So Similar: Different Ways of Nb(V) and Ta(V) Catecholate Complexation.
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ABSTRACT:
SUBMITTER: Abramov PA
PROVIDER: S-EPMC10361208 | biostudies-literature | 2023 Jun
REPOSITORIES: biostudies-literature
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Not So Similar: Different Ways of Nb(V) and Ta(V) Catecholate Complexation.
Abramov Pavel A PA Sokolov Maxim N MN
Molecules (Basel, Switzerland) 20230622 13
The reactions between catechol (H<sub>2</sub>cat) and niobium(V) or tantalum(V) precursors in basic aqueous solutions lead to the formation of catecholate complexes of different natures. The following complexes were isolated and characterized by single-crystal X-ray diffraction (SCXRD): (<b>1</b>) (NH<sub>4</sub>)<sub>3</sub>[NbO(cat)<sub>3</sub>]∙4H<sub>2</sub>O; (<b>2</b>) K<sub>2</sub>[Nb(cat)<sub>3</sub>(Hcat)]·2H<sub>2</sub>cat·2H<sub>2</sub>O; (<b>3</b>) Cs<sub>3</sub>[NbO(cat)<sub>3</sub> ...[more]
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