Dataset Information

Upgrading Pyrolytic Residue from End-of-Life Tires to Efficient Heterogeneous Catalysts for the Conversion of Glycerol to Acetins.

ABSTRACT: Recovered carbon blacks (rCBs) produced from end-of-life tires using pyrolysis were transformed into solid acid catalysts for the synthesis of acetins, i.e., products with a wide spectrum of practical applications. Tuning the chemical properties of the surface of samples and introducing specific functional groups on the rCBs were achieved through carbon functionalization with concentrated H₂SO₄. The initial and modified rCBs were thoroughly characterized using techniques such as elemental analysis, potentiometric back titration, thermogravimetric technique, scanning and transmission microscopy, X-ray photoelectron spectroscopy, etc. The catalytic activities of the samples were measured via batch mode glycerol acetylation performed at 110 °C and compared to the catalytic performance of the functionalized commercial carbon black. The modified rCBs were found to show a significant catalytic effect in the tested reaction, giving high glycerol conversions (above 95%) and satisfactory combined yields of diacetins and triacetin (~72%) within 4 h; this behavior was attributed to the presence of -SO₃H moieties on the surface of functionalized rCBs. The reusability tests indicated that the modified samples were catalytically stable in subsequent acetylation runs. The obtained results evidenced the feasibility of using end-of-life tires for the production of effective acid catalysts for glycerol valorization processes.

SUBMITTER: Malaika A

PROVIDER: S-EPMC10745658 | biostudies-literature | 2023 Dec

REPOSITORIES: biostudies-literature

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Upgrading Pyrolytic Residue from End-of-Life Tires to Efficient Heterogeneous Catalysts for the Conversion of Glycerol to Acetins.

Malaika Anna A Kowalska-Kuś Jolanta J Końska Klaudia K Ptaszyńska Karolina K Jankowska Aldona A Held Agnieszka A Wróblewski Krzysztof K Kozłowski Mieczysław M

Molecules (Basel, Switzerland) 20231217 24

Recovered carbon blacks (rCBs) produced from end-of-life tires using pyrolysis were transformed into solid acid catalysts for the synthesis of acetins, i.e., products with a wide spectrum of practical applications. Tuning the chemical properties of the surface of samples and introducing specific functional groups on the rCBs were achieved through carbon functionalization with concentrated H<sub>2</sub>SO<sub>4</sub>. The initial and modified rCBs were thoroughly characterized using techniques su ...[more]

PMID: 38138625

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Project description:Glycerol is an eco-friendly solvent that enhances plant biomass decomposition via glycerolysis in many pretreatment methods. Nonetheless, inefficient conversion of glycerol to ethanol by natural Saccharomyces cerevisiae limits its use in these processes. In this study, we have developed an efficient glycerol-converting yeast strain by genetically modifying the oxidation of cytosolic NAD (NADH) by an O2-dependent dynamic shuttle and abolishing both glycerol phosphorylation and biosynthesis in S. cerevisiae strain D452-2, as well as by vigorous expression of whole genes in the dihydroxyacetone (DHA) pathway (Candida utilis glycerol facilitator, Ogataea polymorpha glycerol dehydrogenase, endogenous dihydroxyacetone kinase, and triosephosphate isomerase). The engineered strain showed conversion efficiencies (CE) up to 0.49 g ethanol/g glycerol (98% of theoretical CE), with a production rate of >1 g liter-1 h-1 when glycerol was supplemented in a single fed-batch fermentation in a rich medium. Furthermore, the engineered strain converted a mixture of glycerol and glucose into bioethanol (>86 g/liter) with 92.8% CE. To the best of our knowledge, this is the highest reported titer of bioethanol produced from glycerol and glucose. Notably, we developed a glycerol-utilizing transformant from a parent strain which cannot utilize glycerol as a sole carbon source. The developed strain converted glycerol to ethanol with a productivity of 0.44 g liter-1 h-1 on minimal medium under semiaerobic conditions. Our findings will promote the utilization of glycerol in eco-friendly biorefineries and integrate bioethanol and plant oil industries. IMPORTANCE With the development of efficient lignocellulosic biorefineries, glycerol has attracted attention as an eco-friendly biomass-derived solvent that can enhance the dissociation of lignin and cell wall polysaccharides during the pretreatment process. Coconversion of glycerol with the sugars released from biomass after glycerolysis increases the resources for ethanol production and lowers the burden of component separation. However, low conversion efficiency from glycerol and sugars limits the industrial application of this process. Therefore, the generation of an efficient glycerol-fermenting yeast will promote the applicability of integrated biorefineries. Hence, metabolic flux control in yeast grown on glycerol will lead to the generation of cell factories that produce chemicals, which will boost biodiesel and bioethanol industries. Additionally, the use of glycerol-fermenting yeast will reduce global warming and generation of agricultural waste, leading to the establishment of a sustainable society.

Dataset Information

Upgrading Pyrolytic Residue from End-of-Life Tires to Efficient Heterogeneous Catalysts for the Conversion of Glycerol to Acetins.

Publications

Upgrading Pyrolytic Residue from End-of-Life Tires to Efficient Heterogeneous Catalysts for the Conversion of Glycerol to Acetins.

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