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Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes.

ABSTRACT: This report presents a selective synthetic approach towards borazine from ammonia borane using a dinuclear rhodium olefin homogeneous catalyst. The synthesis and spectroscopic characterization of a dirhodium ammonia borane complex as an intermediate provides insight into a possible mode of activation.

SUBMITTER: Jurt P

PROVIDER: S-EPMC11323292 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature

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Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes.

Jurt Pascal P Gamboa-Carballo Juan José JJ Schweinzer Clara C Himmelbauer Daniel D Thöny Debora D Gianetti Thomas L TL Trincado Monica M Grützmacher Hansjörg H

Dalton transactions (Cambridge, England : 2003) 20240827 34

This report presents a selective synthetic approach towards borazine from ammonia borane using a dinuclear rhodium olefin homogeneous catalyst. The synthesis and spectroscopic characterization of a dirhodium ammonia borane complex as an intermediate provides insight into a possible mode of activation. ...[more]

PMID: 39140315

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