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Chiral trimethylsilylated C2-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by 1H NMR.


ABSTRACT: The use of organophosphorus derivatising agents, prepared from C2 symmetric trimethylsilylated diamines, for the 1H NMR and 31P NMR determination of the enantiomeric composition of chiral alcohols is described.

SUBMITTER: Chauvin AS 

PROVIDER: S-EPMC1483824 | biostudies-literature | 2006 Mar

REPOSITORIES: biostudies-literature

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Chiral trimethylsilylated C2-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by 1H NMR.

Chauvin Anne-Sophie AS   Alexakis Alexandre A  

Beilstein journal of organic chemistry 20060328


The use of organophosphorus derivatising agents, prepared from C2 symmetric trimethylsilylated diamines, for the 1H NMR and 31P NMR determination of the enantiomeric composition of chiral alcohols is described. ...[more]

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