Ontology highlight
ABSTRACT:
SUBMITTER: Joyce LA
PROVIDER: S-EPMC3179184 | biostudies-literature | 2011 Aug
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20110803 34
The association between an achiral copper(II) host (1) and chiral carboxylate guests was studied using exciton-coupled circular dichroism (ECCD). Enantiomeric complexes were created upon binding of the enantiomers of the carboxylate guests to the host, and the sign of the resultant CD signal allowed for determination of the configuration of the studied guest. The difference in magnitudes and shapes of the CD signals, in conjunction with linear discriminant analysis (LDA), allowed for the identit ...[more]