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Revised structure of deacetyl-1,10-didehydrosalvinorin G.

ABSTRACT: In comparison with the NMR data of salvinorin A and its 8-epimer, the published structure of deacetyl-1,10-didehydrosalvinorin G was revised to its 8-epimer. The stereochemistry of 8-epi-deacetyl-1,10-didehydrosalvinorin G was further confirmed by NOESY and chemical synthesis.

SUBMITTER: Ma Z

PROVIDER: S-EPMC2390872 | biostudies-literature | 2007 Jul

REPOSITORIES: biostudies-literature

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Revised structure of deacetyl-1,10-didehydrosalvinorin G.

Ma Zhongze Z Lee David Y W DY

Tetrahedron letters 20070701 31

In comparison with the NMR data of salvinorin A and its 8-epimer, the published structure of deacetyl-1,10-didehydrosalvinorin G was revised to its 8-epimer. The stereochemistry of 8-epi-deacetyl-1,10-didehydrosalvinorin G was further confirmed by NOESY and chemical synthesis. ...[more]

PMID: 18665199

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