Unknown

Dataset Information

0

Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: ligand-controlled regioselectivity.


ABSTRACT: Through computational and experimental studies, the mechanisms of gold-catalyzed cycloisomerization of bromoallenyl ketones in toluene have been elucidated. The divergent 1,2-migrations for the Au(I)- and Au(III)-catalyzed reactions have been investigated, and the results confirmed that the regiochemistry is ligand-dependent in cases of Au(PR3)L (L = Cl, OTf, BF4, and SbF6) catalysts.

SUBMITTER: Xia Y 

PROVIDER: S-EPMC2435085 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

altmetric image

Publications

Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: ligand-controlled regioselectivity.

Xia Yuanzhi Y   Dudnik Alexander S AS   Gevorgyan Vladimir V   Li Yahong Y  

Journal of the American Chemical Society 20080508 22


Through computational and experimental studies, the mechanisms of gold-catalyzed cycloisomerization of bromoallenyl ketones in toluene have been elucidated. The divergent 1,2-migrations for the Au(I)- and Au(III)-catalyzed reactions have been investigated, and the results confirmed that the regiochemistry is ligand-dependent in cases of Au(PR3)L (L = Cl, OTf, BF4, and SbF6) catalysts. ...[more]

Similar Datasets

| S-EPMC6535146 | biostudies-literature
| S-EPMC7496544 | biostudies-literature
| S-EPMC4120096 | biostudies-literature
| S-EPMC7173349 | biostudies-literature
| S-EPMC3774677 | biostudies-literature
| S-EPMC3998771 | biostudies-literature
| S-EPMC3778415 | biostudies-literature
| S-EPMC9490818 | biostudies-literature
| S-EPMC5949847 | biostudies-other
| S-EPMC2995695 | biostudies-literature