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Access to the protoilludane core by gold-catalyzed allene-vinylcyclopropane cycloisomerization.

ABSTRACT: Gold(I)-catalyzed allene-vinylcyclopropane cycloisomerization leads to the tricyclic framework of the protoilludanes in a single step by a reaction that involves a cyclopropane ring expansion and a Prins cyclization.

SUBMITTER: Pitaval A

PROVIDER: S-EPMC3774677 | biostudies-literature | 2013 Sep

REPOSITORIES: biostudies-literature

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Access to the protoilludane core by gold-catalyzed allene-vinylcyclopropane cycloisomerization.

Pitaval Anthony A Leboeuf David D Ceccon Julien J Echavarren Antonio M AM

Organic letters 20130820 17

Gold(I)-catalyzed allene-vinylcyclopropane cycloisomerization leads to the tricyclic framework of the protoilludanes in a single step by a reaction that involves a cyclopropane ring expansion and a Prins cyclization. ...[more]

PMID: 23962171

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