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Access to the protoilludane core by gold-catalyzed allene-vinylcyclopropane cycloisomerization.


ABSTRACT: Gold(I)-catalyzed allene-vinylcyclopropane cycloisomerization leads to the tricyclic framework of the protoilludanes in a single step by a reaction that involves a cyclopropane ring expansion and a Prins cyclization.

SUBMITTER: Pitaval A 

PROVIDER: S-EPMC3774677 | biostudies-literature | 2013 Sep

REPOSITORIES: biostudies-literature

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Access to the protoilludane core by gold-catalyzed allene-vinylcyclopropane cycloisomerization.

Pitaval Anthony A   Leboeuf David D   Ceccon Julien J   Echavarren Antonio M AM  

Organic letters 20130820 17


Gold(I)-catalyzed allene-vinylcyclopropane cycloisomerization leads to the tricyclic framework of the protoilludanes in a single step by a reaction that involves a cyclopropane ring expansion and a Prins cyclization. ...[more]

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