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Efficient protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds using tetrabutylammonium fluoride.

ABSTRACT: [reaction: see text] The protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds proceeds efficiently by treatment with tetrabutylammonium fluoride in wet DMF or THF via isolable dimethylsilanol intermediates.

SUBMITTER: Heitzman CL 

PROVIDER: S-EPMC2515625 | biostudies-literature | 2005 Jun

REPOSITORIES: biostudies-literature

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Efficient protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds using tetrabutylammonium fluoride.

Heitzman Cheryl L CL   Lambert William T WT   Mertz Eric E   Shotwell J Brad JB   Tinsley Jennifer M JM   Va Porino P   Roush William R WR  

Organic letters 20050601 12

[reaction: see text] The protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds proceeds efficiently by treatment with tetrabutylammonium fluoride in wet DMF or THF via isolable dimethylsilanol intermediates. ...[more]

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