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Triple-Decker Complexes Formed via the Weak Link Approach.

ABSTRACT: Through the weak link approach and a halide-induced ligand rearrangement process, semi-open and condensed triple-decker complexes (TDCs) were prepared and fully characterized. These triple-decker structures with tailorable layers through choice of hemilabile ligand starting materials can be chemically opened and closed to expose the interior layer in a reversible fashion using small-molecule and elemental anion ligand substitution reactions.

SUBMITTER: Jeon YM 

PROVIDER: S-EPMC2593806 | biostudies-literature | 2006 May

REPOSITORIES: biostudies-literature

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Triple-Decker Complexes Formed via the Weak Link Approach.

Jeon You-Moon YM   Heo Jungseok J   Brown Aaron M AM   Mirkin Chad A CA  

Organometallics 20060501 11

Through the weak link approach and a halide-induced ligand rearrangement process, semi-open and condensed triple-decker complexes (TDCs) were prepared and fully characterized. These triple-decker structures with tailorable layers through choice of hemilabile ligand starting materials can be chemically opened and closed to expose the interior layer in a reversible fashion using small-molecule and elemental anion ligand substitution reactions. ...[more]

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