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Straightforward and Controlled Synthesis of Porphyrin-Phthalocyanine-Porphyrin Heteroleptic Triple-Decker Assemblies.


ABSTRACT: A versatile and straightforward protocol is disclosed for controlled synthesis of complex lanthanide-bridged heteroleptic porphyrin-phthalocyanine triple-decker assemblies. Two porphyrins, linked by a flexible spacer chain of intermediate length, sequentially capture lanthanide ions and a phthalocyanine to efficiently form the triple-decker complex. The bridge directs assembly, but also controls the mobility of the central macrocycle and further imparts a fully eclipsed arrangement of all three rings.

SUBMITTER: Gonzalez-Lucas D 

PROVIDER: S-EPMC7497087 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature

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Straightforward and Controlled Synthesis of Porphyrin-Phthalocyanine-Porphyrin Heteroleptic Triple-Decker Assemblies.

González-Lucas Daniel D   Soobrattee Shazia C SC   Hughes David L DL   Tizzard Graham J GJ   Coles Simon J SJ   Cammidge Andrew N AN  

Chemistry (Weinheim an der Bergstrasse, Germany) 20200727 47


A versatile and straightforward protocol is disclosed for controlled synthesis of complex lanthanide-bridged heteroleptic porphyrin-phthalocyanine triple-decker assemblies. Two porphyrins, linked by a flexible spacer chain of intermediate length, sequentially capture lanthanide ions and a phthalocyanine to efficiently form the triple-decker complex. The bridge directs assembly, but also controls the mobility of the central macrocycle and further imparts a fully eclipsed arrangement of all three  ...[more]

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