Ontology highlight
ABSTRACT:
SUBMITTER: Gonzalez-Lucas D
PROVIDER: S-EPMC7497087 | biostudies-literature | 2020 May
REPOSITORIES: biostudies-literature
González-Lucas Daniel D Soobrattee Shazia C SC Hughes David L DL Tizzard Graham J GJ Coles Simon J SJ Cammidge Andrew N AN
Chemistry (Weinheim an der Bergstrasse, Germany) 20200727 47
A versatile and straightforward protocol is disclosed for controlled synthesis of complex lanthanide-bridged heteroleptic porphyrin-phthalocyanine triple-decker assemblies. Two porphyrins, linked by a flexible spacer chain of intermediate length, sequentially capture lanthanide ions and a phthalocyanine to efficiently form the triple-decker complex. The bridge directs assembly, but also controls the mobility of the central macrocycle and further imparts a fully eclipsed arrangement of all three ...[more]