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An efficient and general approach to beta-functionalized ketones.


ABSTRACT: [structure: see text]. The oxidation of selected anions (N3-, SCN-, I-, and Br-) by ceric ammonium nitrate (CAN) in the presence of substituted cyclopropyl alcohols provides a novel approach to beta-functionalized ketones. The protocol has a number of advantages including short reaction times, ease of reagent handling, and mild, neutral reaction conditions. Overall, this method provides an alternative pathway to important starting materials and intermediates in organic synthesis.

SUBMITTER: Jiao J 

PROVIDER: S-EPMC2593908 | biostudies-literature | 2007 Mar

REPOSITORIES: biostudies-literature

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An efficient and general approach to beta-functionalized ketones.

Jiao Jingliang J   Nguyen Larry X LX   Patterson Dennis R DR   Flowers Robert A RA  

Organic letters 20070303 7


[structure: see text]. The oxidation of selected anions (N3-, SCN-, I-, and Br-) by ceric ammonium nitrate (CAN) in the presence of substituted cyclopropyl alcohols provides a novel approach to beta-functionalized ketones. The protocol has a number of advantages including short reaction times, ease of reagent handling, and mild, neutral reaction conditions. Overall, this method provides an alternative pathway to important starting materials and intermediates in organic synthesis. ...[more]

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