Ontology highlight
ABSTRACT:
SUBMITTER: Liou LR
PROVIDER: S-EPMC2636850 | biostudies-literature | 2008 Apr
REPOSITORIES: biostudies-literature
Liou Lara R LR McNeil Anne J AJ Ramirez Antonio A Toombes Gilman E S GE Gruver Jocelyn M JM Collum David B DB
Journal of the American Chemical Society 20080313 14
The method of continuous variation in conjunction with 6Li NMR spectroscopy was used to characterize lithium enolates derived from 1-indanone, cyclohexanone, and cyclopentanone in solution. The strategy relies on forming ensembles of homo- and heteroaggregated enolates. The enolates form exclusively chelated dimers in N,N,N',N'-tetramethylethylenediamine and cubic tetramers in tetrahydrofuran and 1,2-dimethoxyethane. ...[more]