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Lithium enolates of simple ketones: structure determination using the method of continuous variation.


ABSTRACT: The method of continuous variation in conjunction with 6Li NMR spectroscopy was used to characterize lithium enolates derived from 1-indanone, cyclohexanone, and cyclopentanone in solution. The strategy relies on forming ensembles of homo- and heteroaggregated enolates. The enolates form exclusively chelated dimers in N,N,N',N'-tetramethylethylenediamine and cubic tetramers in tetrahydrofuran and 1,2-dimethoxyethane.

SUBMITTER: Liou LR 

PROVIDER: S-EPMC2636850 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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Lithium enolates of simple ketones: structure determination using the method of continuous variation.

Liou Lara R LR   McNeil Anne J AJ   Ramirez Antonio A   Toombes Gilman E S GE   Gruver Jocelyn M JM   Collum David B DB  

Journal of the American Chemical Society 20080313 14


The method of continuous variation in conjunction with 6Li NMR spectroscopy was used to characterize lithium enolates derived from 1-indanone, cyclohexanone, and cyclopentanone in solution. The strategy relies on forming ensembles of homo- and heteroaggregated enolates. The enolates form exclusively chelated dimers in N,N,N',N'-tetramethylethylenediamine and cubic tetramers in tetrahydrofuran and 1,2-dimethoxyethane. ...[more]

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