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Electronic and steric effects on the rate of the traceless Staudinger ligation.

ABSTRACT: Interplay between electronic effects imparted by phosphinothiol substituents and steric effects imposed by amino-acid reactants affects the rate of the traceless Staudinger ligation of peptides in a predictable manner.

SUBMITTER: Tam A 

PROVIDER: S-EPMC2715360 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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Electronic and steric effects on the rate of the traceless Staudinger ligation.

Tam Annie A   Soellner Matthew B MB   Raines Ronald T RT  

Organic & biomolecular chemistry 20080303 7

Interplay between electronic effects imparted by phosphinothiol substituents and steric effects imposed by amino-acid reactants affects the rate of the traceless Staudinger ligation of peptides in a predictable manner. ...[more]

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