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A traceless Staudinger reagent to deliver diazirines.

ABSTRACT: A triarylphosphine reagent that reacts with organic azides to install amide-linked diazirines is reported. This traceless Staudinger reagent reacts with complex organic azides to yield amide-linked diazirines, thus expanding the scope of the utility of both azide and diazirine chemistry.

SUBMITTER: Ahad AM 

PROVIDER: S-EPMC3857746 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature

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A traceless Staudinger reagent to deliver diazirines.

Ahad Ali M AM   Jensen Stephanie M SM   Jewett John C JC  

Organic letters 20130923 19

A triarylphosphine reagent that reacts with organic azides to install amide-linked diazirines is reported. This traceless Staudinger reagent reacts with complex organic azides to yield amide-linked diazirines, thus expanding the scope of the utility of both azide and diazirine chemistry. ...[more]

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