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Titanocene(III) chloride-mediated reductions of oxazines, hydroxamic acids, and N-hydroxy carbamates.

ABSTRACT: Titanocene(III) chloride (Cp(2)TiCl), generated in situ, reduces N-O bonds of various substrates in good to excellent yields (72-95%). Reactions may be performed with stoichiometric Cp(2)TiCl or with catalytic Cp(2)TiCl.

SUBMITTER: Cesario C

PROVIDER: S-EPMC2725442 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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Titanocene(III) chloride-mediated reductions of oxazines, hydroxamic acids, and N-hydroxy carbamates.

Cesario Cara C Tardibono Lawrence P LP Miller Marvin J MJ

The Journal of organic chemistry 20090101 1

Titanocene(III) chloride (Cp(2)TiCl), generated in situ, reduces N-O bonds of various substrates in good to excellent yields (72-95%). Reactions may be performed with stoichiometric Cp(2)TiCl or with catalytic Cp(2)TiCl. ...[more]

PMID: 19053586

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