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Titanocene(III)-catalyzed formation of indolines and azaindolines.

ABSTRACT: Reductive cyclization of epoxides tethered to substituted anilines and aminopyridines in the presence of 3 mol % of titanocene dichloride and stoichiometric manganese metal promotes a radical annulation to form 3,3-disubstituted indolines and azaindolines.

SUBMITTER: Wipf P 

PROVIDER: S-EPMC5467310 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Titanocene(III)-catalyzed formation of indolines and azaindolines.

Wipf Peter P   Maciejewski John P JP  

Organic letters 20080910 19

Reductive cyclization of epoxides tethered to substituted anilines and aminopyridines in the presence of 3 mol % of titanocene dichloride and stoichiometric manganese metal promotes a radical annulation to form 3,3-disubstituted indolines and azaindolines. ...[more]

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