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Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines.

ABSTRACT: A cationic (CAAC)gold(I) complex promotes the addition of all types of nontertiary amines to a variety of allenes, affording allylic amines in good to excellent yields; the amino fragment always adds to the less substituted terminus of the CCC skeleton.

SUBMITTER: Zeng X 

PROVIDER: S-EPMC2739117 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines.

Zeng Xiaoming X   Soleilhavoup Michele M   Bertrand Guy G  

Organic letters 20090801 15

A cationic (CAAC)gold(I) complex promotes the addition of all types of nontertiary amines to a variety of allenes, affording allylic amines in good to excellent yields; the amino fragment always adds to the less substituted terminus of the CCC skeleton. ...[more]

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