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Gold(I)-Catalyzed Enantioselective Intramolecular Hydroamination of Allenes with Ureas.

ABSTRACT: Enantioselective intramolecular hydroamination of N-allenyl ureas catalyzed by an enantiomerically enriched bis(gold) phosphine complex forms pyrrolidine derivatives in good yield with up to 93% ee.

SUBMITTER: Li H 

PROVIDER: S-EPMC3169097 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Gold(I)-Catalyzed Enantioselective Intramolecular Hydroamination of Allenes with Ureas.

Li Hao H   Lee Seong Du SD   Widenhoefer Ross A RA  

Journal of organometallic chemistry 20110101 1

Enantioselective intramolecular hydroamination of N-allenyl ureas catalyzed by an enantiomerically enriched bis(gold) phosphine complex forms pyrrolidine derivatives in good yield with up to 93% ee. ...[more]

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