Unknown

Dataset Information

0

Palladium-catalyzed asymmetric dearomatization of naphthalene derivatives.

ABSTRACT: An intramolecular enantioselective metal-catalyzed dearomatization reaction is described. This procedure allows the dearomatization of naphthalene derivatives through an electrophilic aromatic substitution-type reaction on a Pd(II) intermediate. The high yields and enantioselectivities achieved make this procedure a valuable method for synthetic chemists.

SUBMITTER: Garcia-Fortanet J 

PROVIDER: S-EPMC2748791 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Palladium-catalyzed asymmetric dearomatization of naphthalene derivatives.

García-Fortanet Jorge J   Kessler Florian F   Buchwald Stephen L SL  

Journal of the American Chemical Society 20090501 19

An intramolecular enantioselective metal-catalyzed dearomatization reaction is described. This procedure allows the dearomatization of naphthalene derivatives through an electrophilic aromatic substitution-type reaction on a Pd(II) intermediate. The high yields and enantioselectivities achieved make this procedure a valuable method for synthetic chemists. ...[more]

Similar Datasets

Unknown Palladium(0)-catalyzed arylative dearomatization of phenols.
| S-EPMC3124856 | biostudies-literature
Unknown Palladium-Catalyzed Asymmetric Allylic Alkylations with Toluene Derivatives as Pronucleophiles.
| S-EPMC4836847 | biostudies-literature
Unknown Catalytic asymmetric hydroxylative dearomatization of 2-naphthols: synthesis of lacinilene derivatives.
| S-EPMC5625263 | biostudies-literature
Unknown Palladium-catalyzed asymmetric [3 + 2] trimethylenemethane cycloaddition reactions.
| S-EPMC2535802 | biostudies-literature
Unknown Asymmetric palladium-catalyzed hydroarylation of styrenes and dienes.
| S-EPMC3129978 | biostudies-literature
Unknown Asymmetric palladium-catalyzed directed intermolecular fluoroarylation of styrenes.
| S-EPMC3971964 | biostudies-literature
Unknown Photocatalytic Palladium-Catalyzed Fluoroalkylation of Styrene Derivatives.
| S-EPMC7587045 | biostudies-literature
Unknown Palladium-catalyzed enantioselective alkenylation of alkenylbenzene derivatives.
| S-EPMC6685350 | biostudies-literature
Unknown Evidence for Simultaneous Dearomatization of Two Aromatic Rings under Mild Conditions in Cu(I)-Catalyzed Direct Asymmetric Dearomatization of Pyridine.
| S-EPMC8171382 | biostudies-literature
Unknown Palladium-catalyzed asymmetric ring expansion of allenylcyclobutanols: an asymmetric Wagner-Meerwein shift.
| S-EPMC2585988 | biostudies-literature