Ontology highlight
ABSTRACT:
SUBMITTER: Rousseaux S
PROVIDER: S-EPMC3124856 | biostudies-literature | 2011 Jun
REPOSITORIES: biostudies-literature
Rousseaux Sophie S García-Fortanet Jorge J Del Aguila Sanchez Miguel Angel MA Buchwald Stephen L SL
Journal of the American Chemical Society 20110525 24
The palladium-catalyzed arylative dearomatization of phenols to yield spirocyclohexadienone products in good to excellent yields has been developed. Preliminary results demonstrate that the formation of the spirocyclic all-carbon quaternary center can be accomplished with high levels of enantiocontrol (up to 91% ee). ...[more]