Ontology highlight
ABSTRACT:
SUBMITTER: Du H
PROVIDER: S-EPMC2776772 | biostudies-literature | 2008 Jul
REPOSITORIES: biostudies-literature
Du Haifeng H Zhao Baoguo B Shi Yian Y
Journal of the American Chemical Society 20080613 27
This paper describes a catalytic asymmetric diamination process for terminal olefins at allylic and homoallylic carbons via formal C-H activation using di-tert-butyldiaziridinone as nitrogen source with a catalyst generated from Pd2(dba)3 and chiral phosphorus amidite ligand. A wide variety of readily available terminal olefins can be effectively diaminated in good yields with high regio-, diastereo-, and enantioselectivities. ...[more]