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Asymmetric epoxidation of fluoroolefins by chiral dioxirane. Fluorine effect on enantioselectivity.

ABSTRACT: The asymmetric epoxidation of various fluoroolefins has been studied using chiral ketone catalyst, and up to 93% ee was achieved with fructose-derived ketone 1.

SUBMITTER: Wong OA

PROVIDER: S-EPMC2784290 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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Asymmetric epoxidation of fluoroolefins by chiral dioxirane. Fluorine effect on enantioselectivity.

Wong O Andrea OA Shi Yian Y

The Journal of organic chemistry 20091101 21

The asymmetric epoxidation of various fluoroolefins has been studied using chiral ketone catalyst, and up to 93% ee was achieved with fructose-derived ketone 1. ...[more]

PMID: 19795858

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