Ontology highlight
ABSTRACT:
SUBMITTER: Gonzalez AZ
PROVIDER: S-EPMC2798906 | biostudies-literature | 2010 Jan
REPOSITORIES: biostudies-literature
González Ana Z AZ Toste F Dean FD
Organic letters 20100101 1
An enantioselective gold(I)-catalyzed intramolecular [4 + 2]-cycloaddition of allenes and dienes is reported. The reactions allow for the asymmetric synthesis of trans-hexahydroindenes and pyrrolidine products using C(3)-symmetric phosphitegold(I) and ortho-arylphosphoramiditegold(I) complexes as catalysts, respectively. ...[more]