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Rhodium-Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids.

ABSTRACT: Transformation of aromatic thioesters into arylboronic esters was achieved efficiently using a rhodium catalyst. The broad functional-group tolerance and mild conditions of the method have allowed for the two-step decarboxylative borylation of a wide range of aromatic carboxylic acids, including commercially available drugs.

SUBMITTER: Ochiai H

PROVIDER: S-EPMC5324605 | biostudies-literature | 2017 Feb

REPOSITORIES: biostudies-literature

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Rhodium-Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids.

Ochiai Hidenori H Uetake Yuta Y Niwa Takashi T Hosoya Takamitsu T

Angewandte Chemie (International ed. in English) 20170126 9

Transformation of aromatic thioesters into arylboronic esters was achieved efficiently using a rhodium catalyst. The broad functional-group tolerance and mild conditions of the method have allowed for the two-step decarboxylative borylation of a wide range of aromatic carboxylic acids, including commercially available drugs. ...[more]

PMID: 28124826

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