Ontology highlight
ABSTRACT:
SUBMITTER: Zhang ZT
PROVIDER: S-EPMC2827299 | biostudies-literature | 2010 Feb
REPOSITORIES: biostudies-literature
Organic letters 20100201 4
The trichlorophenyl,- dichlorodiphenyl,- and chlorotriphenylgermanes undergo Pd-catalyzed cross-couplings with aryl bromides and iodides in the presence of TBAF in toluene with addition of the measured amount of water. One chloride ligand on the Ge center allows efficient activation by fluoride to promote transfer of one, two, or three phenyl groups from the organogermane precursors. ...[more]