Ontology highlight
ABSTRACT:
SUBMITTER: Molander GA
PROVIDER: S-EPMC2829831 | biostudies-literature | 2008 Sep
REPOSITORIES: biostudies-literature
The Journal of organic chemistry 20080806 17
A number of alkynyl pinacolboronates bearing various functional groups were synthesized according to literature methods. These were then stereoselectively reduced to the cis-alkenyl pinacolboronates via hydroboration with dicyclohexylborane followed by chemoselective protodeboronation using acetic acid. Treatment with potassium hydrogen fluoride smoothly converted these to the corresponding potassium organotrifluoroborates. ...[more]