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One-Pot, Highly Stereoselective Synthesis of Dithioacetal-?,?-Diglycosides.

ABSTRACT: A one-step access to dithioacetal-?,?-diglycosides is reported. The synthetic strategy is based on the thioacetalization of aldehydes or ketones via highly stereoselective ring-opening of 1,6 anhydrosugars with bis(trimethylsilyl)sulfide.

SUBMITTER: Cespedes Davila MF

PROVIDER: S-EPMC6017313 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature

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One-Pot, Highly Stereoselective Synthesis of Dithioacetal-α,α-Diglycosides.

Céspedes Dávila Maria F MF Schneider Jérémy P JP Godard Amélie A Hazelard Damien D Compain Philippe P

Molecules (Basel, Switzerland) 20180415 4

A one-step access to dithioacetal-α,α-diglycosides is reported. The synthetic strategy is based on the thioacetalization of aldehydes or ketones via highly stereoselective ring-opening of 1,6 anhydrosugars with bis(trimethylsilyl)sulfide. ...[more]

PMID: 29662042

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