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Carborane-based pincers: synthesis and structure of SeBSe and SBS Pd(II) complexes.

ABSTRACT: We report the synthesis of several unique, boron-rich pincer complexes derived from m-carborane. The SeBSe and SBS pincer ligands can be synthesized via two independent synthetic routes and are metalated with Pd(II). These structures represent unique coordinating motifs, each with a Pd-B(2) bond chelated by two thio- or selenoether ligands. This class of structures serves as the first example of boron-metal pincer complexes and possesses several interesting electronic properties imposed by the m-carborane cage.

SUBMITTER: Spokoyny AM

PROVIDER: S-EPMC2842188 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Carborane-based pincers: synthesis and structure of SeBSe and SBS Pd(II) complexes.

Spokoyny Alexander M AM Reuter Matthew G MG Stern Charlotte L CL Ratner Mark A MA Seideman Tamar T Mirkin Chad A CA

Journal of the American Chemical Society 20090701 27

We report the synthesis of several unique, boron-rich pincer complexes derived from m-carborane. The SeBSe and SBS pincer ligands can be synthesized via two independent synthetic routes and are metalated with Pd(II). These structures represent unique coordinating motifs, each with a Pd-B(2) bond chelated by two thio- or selenoether ligands. This class of structures serves as the first example of boron-metal pincer complexes and possesses several interesting electronic properties imposed by the m ...[more]

PMID: 19583431

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