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Mononuclear Perfluoroalkyl-Heterocyclic Complexes of Pd(II): Synthesis, Structural Characterization and Antimicrobial Activity.


ABSTRACT: Two mononuclear Pd(II) complexes [PdCl2(pfptp)] (1) and [PdCl2(pfhtp)] (2), with ligands 2-(3-perfluoropropyl-1-methyl-1,2,4-triazole-5yl)-pyridine (pfptp) and 2-(3-perfluoroheptyl-1-methyl-1,2,4-triazole-5yl)-pyridine (pfhtp), were synthesized and structurally characterized. The two complexes showed a bidentate coordination of the ligand occurring through N atom of pyridine ring and N4 atom of 1,2,4-triazole. Both complexes showed antimicrobial activity when tested against both Gram-negative and Gram-positive bacterial strains.

SUBMITTER: Rubino S 

PROVIDER: S-EPMC7582383 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

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Mononuclear Perfluoroalkyl-Heterocyclic Complexes of Pd(II): Synthesis, Structural Characterization and Antimicrobial Activity.

Rubino Simona S   Alduina Rosa R   Cancemi Patrizia P   Girasolo Maria Assunta MA   Di Stefano Vita V   Orecchio Santino S   Buscemi Silvestre S   Pibiri Ivana I  

Molecules (Basel, Switzerland) 20200930 19


Two mononuclear Pd(II) complexes [PdCl<sub>2</sub>(pfptp)] (<b>1</b>) and [PdCl<sub>2</sub>(pfhtp)] (<b>2</b>), with ligands 2-(3-perfluoropropyl-1-methyl-1,2,4-triazole-5yl)-pyridine (<b>pfptp</b>) and 2-(3-perfluoroheptyl-1-methyl-1,2,4-triazole-5yl)-pyridine (<b>pfhtp</b>), were synthesized and structurally characterized. The two complexes showed a bidentate coordination of the ligand occurring through N atom of pyridine ring and N4 atom of 1,2,4-triazole. Both complexes showed antimicrobial  ...[more]

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