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An effective C-C double bond formation via Cu(I)-catalyzed dehydrogenation.

ABSTRACT: A dehydrogenation method using Cu(I) and either N,N-di-tert-butylthiadiaziridine 1,1-dioxide or N,N-di-tert-butyldiaziridinone is reported. The dehydrogenation allows a facile introduction of C-C double bond(s) into various carbo- and heterocycles such as oxazolines and thiazolines.

SUBMITTER: Ramirez TA

PROVIDER: S-EPMC2847290 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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An effective C-C double bond formation via Cu(I)-catalyzed dehydrogenation.

Ramirez Thomas A TA Zhao Baoguo B Shi Yian Y

Tetrahedron letters 20100401 14

A dehydrogenation method using Cu(I) and either N,N-di-tert-butylthiadiaziridine 1,1-dioxide or N,N-di-tert-butyldiaziridinone is reported. The dehydrogenation allows a facile introduction of C-C double bond(s) into various carbo- and heterocycles such as oxazolines and thiazolines. ...[more]

PMID: 20368750

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