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New access to H-phosphonates via metal-catalyzed phosphorus-oxygen bond formation.

ABSTRACT: A novel approach to H-phosphonates from hypophosphorous acid using a transfer hydrogenation process was developed. This method is atom-economical, environmentally friendly, catalytic, and efficient, leading easily to H-phosphonate monoesters or ammonium salt in moderate to good yields.

SUBMITTER: Coudray L

PROVIDER: S-EPMC2084078 | biostudies-literature | 2007 Sep

REPOSITORIES: biostudies-literature

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New access to H-phosphonates via metal-catalyzed phosphorus-oxygen bond formation.

Coudray Laëtitia L Abrunhosa-Thomas Isabelle I Montchamp Jean-Luc JL

Tetrahedron letters 20070901 37

A novel approach to H-phosphonates from hypophosphorous acid using a transfer hydrogenation process was developed. This method is atom-economical, environmentally friendly, catalytic, and efficient, leading easily to H-phosphonate monoesters or ammonium salt in moderate to good yields. ...[more]

PMID: 18037974

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