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Synthesis and Characterization of Fused-Ring Iridapyrroles.

ABSTRACT: Treatment of aromatic nitriles with methyllithium produces N-lithiated imine reagents which, when reacted with (?(2)-cyclooctene)(Cl)Ir(PMe(3))(3), generate fused iridaazacycles via ortho-metallation. Mono-protonation of these iridaazacycles produces fused iridapyrrole derivatives, while di-protonation leads to several different pathways.

SUBMITTER: Bleeke JR 

PROVIDER: S-EPMC2850069 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Synthesis and Characterization of Fused-Ring Iridapyrroles.

Bleeke John R JR   Putprasert Phawit P   Thananatthanachon Todsapon T   Rath Nigam P NP  

Organometallics 20081001 22

Treatment of aromatic nitriles with methyllithium produces N-lithiated imine reagents which, when reacted with (η(2)-cyclooctene)(Cl)Ir(PMe(3))(3), generate fused iridaazacycles via ortho-metallation. Mono-protonation of these iridaazacycles produces fused iridapyrrole derivatives, while di-protonation leads to several different pathways. ...[more]

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